...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Inorganic Chemistry Communications >Square-planar nickel(II) complexes with a tridentate Schiff base and monodentate heterocycles: self-assembly to dimeric and one-dimensional array via hydrogen bonding
【24h】

Square-planar nickel(II) complexes with a tridentate Schiff base and monodentate heterocycles: self-assembly to dimeric and one-dimensional array via hydrogen bonding

机译：具有三齿席夫碱和单齿杂环的方形镍（II）配合物：通过氢键自组装成二聚体和一维阵列

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Two nickel(II) complexes having the general formula [Ni(bhac)L] with tridentate ONO-donor acetylacetone benzoylhydrazone (H_2bhac) and monodentate N-donor heterocycles (L = 3,5-dimethylpyrazole (Hdmptz) and imidazole (Himdaz)) are reported. The complexes were synthesized in ethanol media by reacting Ni(O_2CCH_3)_2·4H_2O, H_2bhac and L in 1:!:1 mole ratio and characterized by analytical, magnetic and spectroscopic methods. X-ray crystal structures of both complexes have been determined. In each complex, the metal ion is in square-planar N_2O_2 coordination geometry. In the solid state, a one-dimensional assembly of the [Ni(bhac)(Himidz)] molecules is formed via intermolecular hydrogen bonds between the imidazole N-H groups and the uncoordinated N-atoms of the deprotonated amide functionalities. On the other hand, two [Ni(bhac)(Hdmpz)] molecules are involved in a pair of complementary hdyrogen bonds between the pyrazole N-H groups and the coordinated O-atoms of the deprotonated amide functionalities forming a dinuclear species.
机译：两种具有通式[Ni（bhac）L]的镍（II）配合物，包括三齿ONO供体乙酰丙酮苯甲酰hydr（H_2bhac）和单齿N供体杂环（L = 3,5-二甲基吡唑（Hdmptz）和咪唑（Himdaz））被报道。 Ni（O_2CCH_3）_2·4H_2O，H_2bhac和L以1 ::: 1的摩尔比反应在乙醇介质中合成配合物，并通过分析，磁性和光谱法表征。已经确定了两种配合物的X射线晶体结构。在每个络合物中，金属离子均处于方形N_2O_2配位几何结构。在固态下，[Ni（bhac）（Himidz）]分子的一维组装是通过咪唑N-H基团与去质子化酰胺官能团的未配位N原子之间的分子间氢键形成的。另一方面，两个[Ni（bhac）（Hdmpz）]分子参与了吡唑N-H基团与去质子化酰胺官能团的配位O原子之间的一对互补氢原键，从而形成了双核物质。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号