Supported organometallic complexes. Part 37: synthesis and structures of dimaine-bis(methoxyethyldimethylphosphine) ruthenium(II) complexes

Zhong-Lin Liu; Klaus Eichele; Ekkehard Lindner; Hermann A.Mayer

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Supported organometallic complexes. Part 37: synthesis and structures of dimaine-bis(methoxyethyldimethylphosphine) ruthenium(II) complexes

机译：支持的有机金属配合物。第37部分：二甲基双（甲氧基乙基二甲基膦）钌（II）配合物的合成和结构

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The first two examples of diamineruthenium(II) complexes containing the hemilabile methoxyethyldimethylphosphine ligand, Cl_2Ru(en)(eta~1-Me_2PCH_2CH_2OMe)_2 (2a) and Cl_2Ru[(R,R)-dpen](eta~1-Me_2PCH_2CH_2OMe)_2 (2b) (en = 1,2-diaminoethane, (R,R)-dpen = 1R, 2R-1,2-diamino-1,2-diamino-1,2-diphenylethane) have been synthesized and structurally characterized.

机译：含有半不稳定的甲氧基乙基二甲基膦配体Cl_2Ru（en）（eta〜1-Me_2PCH_2CH_2OMe）_2（2a）和Cl_2Ru [（R，R）-dpen]（eta〜1-Me_2PCH_2CH_2OMe）_2的二胺钌（II）配合物的前两个实例（2b）（en ＝ 1，2-二氨基乙烷，（R，R）-dpen ＝ 1R，2R-1，2-二氨基-1，2-二氨基-1，2-二苯基乙烷）已经合成并在结构上表征。

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来源
《Inorganic Chemistry Communications》 |2003年第4期|共5页
作者
Zhong-Lin Liu; Klaus Eichele; Ekkehard Lindner; Hermann A.Mayer;
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正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
ruthenium(II) complexes; ether-phosphines; diamine ligands; crystal structures;

机译：钌（II）配合物;醚膦;二胺配体;晶体结构;

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1. Supported organometallic complexes. Part 37: synthesis and structures of dimaine-bis(methoxyethyldimethylphosphine) ruthenium(II) complexes [J] . Zhong-Lin Liu, Klaus Eichele, Ekkehard Lindner, Inorganic Chemistry Communications . 2003,第4期

机译：支持的有机金属配合物。第37部分：二甲基双（甲氧基乙基二甲基膦）钌（II）配合物的合成和结构
2. Supported organometallic complexes - Part 34: synthesis and structures of an array of diamine(ether-phosphine)ruthenium(II) complexes and their application in the catalytic hydrogenation of trans-4-phenyl-3-butene-2-one [J] . Lindner E., Warad I., Eichele K., Inorganica Chimica Acta . 2003,第0期

机译：负载有机金属配合物-第34部分：二胺（醚-膦）钌（II）配合物阵列的合成，结构及其在反式4-苯基-3-丁烯-2-酮的催化加氢中的应用
3. Supported organometallic complexes - Part XXXV. Synthesis, characterization, and catalytic application of a new family of diamine(diphosphine)ruthenium(II) complexes [J] . Lindner E., Mayer HA., Warad I., Journal of Organometallic Chemistry . 2003,第1a2期

机译：受支持的有机金属配合物-第XXXV部分。新型二胺（二膦）钌（II）配合物的合成，表征和催化应用
4. Structure of arene-linked dinuclear ruthenium(II) organometallics-peptide complexes [C] . Laure Menin, Iaure Menin, Benjamin S. Murray, International Mass Spectrometry Conference . 2014

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机译：[M（bpy）2氰基]类型的第8组金属配合物的光化学（M =铁，钌）。杂合铁（II）化合物的光合作用和钌（II）化合物的光电离，或者杂合铁（II）化合物的光辅助合成和钌（II）配合物的光电离。
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Supported organometallic complexes. Part 37: synthesis and structures of dimaine-bis(methoxyethyldimethylphosphine) ruthenium(II) complexes

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