A novel 3D organic-inorganic hybrid based on sandwich-type cadmiumhetereopolymolybdate:{[Cd_4(H_2O)_2(2,2'-bpy)_2] Cd[Mo_6O_(12)(OH)_3(PO_4)_2(HPO_4)_2]_2}[Mo_2O_4(2,2'-bpy)_2]_2 centre dot 3H_2O

Hong-Xu Guo; Shi-Xiong Liu

首页> 外文期刊>Inorganic Chemistry Communications >A novel 3D organic-inorganic hybrid based on sandwich-type cadmiumhetereopolymolybdate:{[Cd_4(H_2O)_2(2,2'-bpy)_2] Cd[Mo_6O_(12)(OH)_3(PO_4)_2(HPO_4)_2]_2}[Mo_2O_4(2,2'-bpy)_2]_2 centre dot 3H_2O

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A novel 3D organic-inorganic hybrid based on sandwich-type cadmiumhetereopolymolybdate:{[Cd_4(H_2O)_2(2,2'-bpy)_2] Cd[Mo_6O_(12)(OH)_3(PO_4)_2(HPO_4)_2]_2}[Mo_2O_4(2,2'-bpy)_2]_2 centre dot 3H_2O

机译：一种基于三明治型异质多钼酸镉的新型3D有机-无机杂化物：{[Cd_4（H_2O）_2（2,2'-bpy）_2] Cd [Mo_6O_（12）（OH）_3（PO_4）_2（HPO_4）_2] _2} [Mo_2O_4（2,2'-bpy）_2] _2中心点3H_2O

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The title organic-inorganic hybrid cadmium molybdenum(V) phosphate has been hydrothermally synthesized.The sandwich-type units [Cd_4(H_2O)_2(2,2'-bpy)_2]Cd[Mo_6O_(12)(OH)_3(PO_4)_2(HPO_4)_2_]2 ([Cd_4]Cd[Mo_6P_4]_2) are connected by octahedrally coordinated cadmium into a chain {[Cd_4]Cd[Mo_6P_4]_2}n- The coordination cations [Mo_2O_4(2,2'-bpy)_2]~(2+) link to the neighboring chains,forming a 3D open framework structure.The title complex represents the first sandwich-type cadmium hetereopolymolybdate with 3D network.

机译：已水热合成标题有机-无机杂化钼酸镉钼。三明治型单元[Cd_4（H_2O）_2（2,2'-bpy）_2] Cd [Mo_6O_（12）（OH）_3（PO_4））_2（HPO_4）_2_] 2（[Cd_4] Cd [Mo_6P_4] _2）通过八面体协调的镉连接成链{[Cd_4] Cd [Mo_6P_4] _2} n-配位阳离子[Mo_2O_4（2,2'- bpy）_2]〜（2+）链接到相邻的链，形成3D开放框架结构。标题复合体表示第一个具有3D网络的三明治型镉杂多钼酸镉。

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《Inorganic Chemistry Communications》 |2004年第11期|共4页
作者
Hong-Xu Guo; Shi-Xiong Liu;
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正文语种 eng
中图分类无机化学;
关键词
heteropolyanion; cadmium; 3d network; crystal structure; hydrothermal synthesis;

机译：杂多阴离子镉3d网络晶体结构水热合成;

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1. A novel 3D organic-inorganic hybrid based on sandwich-type cadmiumhetereopolymolybdate:{[Cd_4(H_2O)_2(2,2'-bpy)_2] Cd[Mo_6O_(12)(OH)_3(PO_4)_2(HPO_4)_2]_2}[Mo_2O_4(2,2'-bpy)_2]_2 centre dot 3H_2O [J] . Hong-Xu Guo, Shi-Xiong Liu Inorganic Chemistry Communications . 2004,第11期

机译：一种基于三明治型异质多钼酸镉的新型3D有机-无机杂化物：{[Cd_4（H_2O）_2（2,2'-bpy）_2] Cd [Mo_6O_（12）（OH）_3（PO_4）_2（HPO_4）_2] _2} [Mo_2O_4（2,2'-bpy）_2] _2中心点3H_2O
2. REACTION OF Cd(NO_3)_2 centre dot 4H_2O WITH 4,4'-BIPYRIDINE (bpy) IN MeOH SOLVENT: SYNTHESIS AND CHARACTERIZATION OF T-SHAPED [Cd(bpy)_(1.5)(NO_3)_2] centre dot 3H_2O, SQUARE GRID [Cd(bpy)_2(H_2O)_2](NO_3)_2 centre dot 4H_2O AND LINEAR POLYMERIC [Cd [J] . Jeyagowry T. Sampanthar, Jagadese J. Vittal Crystal engineering . 1999,第4期

机译：Cd（NO_3）_2中心点4H_2O与4,4'-联吡啶（bpy）在MeOH溶剂中的反应：T形[Cd（bpy）_（1.5）（NO_3）_2]中心点3H_2O，SQUARE的合成和表征GRID [Cd（bpy）_2（H_2O）_2]（NO_3）_2中心点4H_2O和线性聚合物[Cd
3. Hydrothermal synthesis and structural characterization of prototypical organic-inorganic hybrid materials: [{Cu(2,2 '-bpy)-(H2O)}(VO)(O3PCH2PO3)], [Cu(2,2 '-bpy)(VO)(O3PCH2CH2PO3)], and [Cu(2,2 '-bpy)(VO)(O3PCH2CH2CH2PO3)]center dot H2O. Bimetallic p [J] . Finn RC., Zubieta J. Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2000,第12期

机译：典型的有机-无机杂化材料的水热合成和结构表征：[{Cu（2,2'-bpy）-（H2O）}（VO）（O3PCH2PO3）]，[Cu（2,2'-bpy）（VO）（O3PCH2CH2PO3）]和[Cu（2,2'-bpy）（VO）（O3PCH2CH2CH2PO3）]中心点H2O。双金属p
4. Synthesis and Electrochemical Characterisation of Ru(2,2'-bpy)33P2W18062 centre dot 15H2O [C] . Tim McCormac The Meeting of the Electrochemical Society . 2003

机译：Ru（2,2'-BPY）3 3 P2W18062中心点15H2O的合成和电化学表征

A novel 3D organic-inorganic hybrid based on sandwich-type cadmiumhetereopolymolybdate:{[Cd_4(H_2O)_2(2,2'-bpy)_2] Cd[Mo_6O_(12)(OH)_3(PO_4)_2(HPO_4)_2]_2}[Mo_2O_4(2,2'-bpy)_2]_2 centre dot 3H_2O

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