Isolation and authentication of a sodium bispyrazolylaluminate

Sara Cortes-Llamas; Miguel-Angel Velazquez-Carmona; Miguel-Angel Munoz-Hernandez

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Isolation and authentication of a sodium bispyrazolylaluminate

机译：双吡唑基铝酸钠的分离与鉴定

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Reaction of [Na(Me_2pz)(thf)]_4 (2) with [(Me_2pz)AlMe_2]_2 in THF generates sodium bispyrazolylaluminate [Na{Al(Me_2pz)_2Me_2}]_(propor.to) (1),the first example of a structurally characterized aluminum analog of a polypyrazolylborate.The X-ray structure of complex 1 shows in the solid state unusual Na-CH_3-Al bridges and pyrazolyl r~5 -coordination to sodium.

机译：[Na（Me_2pz）（thf）] _ 4（2）与THF中的[（Me_2pz）AlMe_2] _2反应生成双吡唑铝酸钠[Na {Al（Me_2pz）_2Me_2}] _（约）（1），第一个配合物1的X射线结构在固态下显示出不寻常的Na-CH_3-Al桥键和吡唑基r〜5-与钠的配位。

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《Inorganic Chemistry Communications》 |2005年第2期|共4页
作者
Sara Cortes-Llamas; Miguel-Angel Velazquez-Carmona; Miguel-Angel Munoz-Hernandez;
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正文语种 eng
中图分类无机化学;
关键词
Main group element chemistry; Pyrazolates; Aluminates; Polydentate ligands;

机译：主族化学;吡唑酸盐;铝酸盐;多齿配体;

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机译：双吡唑基铝酸钠的分离与鉴定
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Isolation and authentication of a sodium bispyrazolylaluminate

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