Synthesis and characteristic of a new arylimido derivative of hexamolybdate with remote strong electro-donating group (Bu_4N)_2[Mo_6O_(18)NC_6H_4N(CH_3)_2-p]

Zicheng Xiao; Yi Zhu; Yongge Wei; Yuan Wang

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Synthesis and characteristic of a new arylimido derivative of hexamolybdate with remote strong electro-donating group (Bu_4N)_2[Mo_6O_(18)NC_6H_4N(CH_3)_2-p]

机译：带有强力给电子基团（Bu_4N）_2 [Mo_6O_（18）NC_6H_4N（CH_3）_2-p]的六钼酸新芳酰胺基衍生物的合成与表征

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A new monofunctionized arylimido derivative of hexamolybdate,(Bu_4N)_2[Mo_6O_(18)NC_6H_4N(CH_3)_2-p],is synthesized by alpha-octamo-lybdate and hydrochloride salt of N,N-dimethyl-1,4-dianiline with DCC as a dehydrating agent.The derivative's crystal data has been obtained and the IR,UV-Vis,~1H NMR spectra and cyclic voltammetry properties have also been studied.

机译：由α-八钼酸盐和N，N-二甲基-1,4-二苯胺盐酸盐与N，N-二甲基-1,4-二苯胺盐酸盐合成六钼酸盐新的单功能芳基酰亚胺衍生物（Bu_4N）_2 [Mo_6O_（18）NC_6H_4N（CH_3）_2-p]。用DCC作为脱水剂。获得了衍生物的晶体数据，并研究了IR，UV-Vis，〜1H NMR谱和循环伏安特性。

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来源
《Inorganic Chemistry Communications》 |2006年第4期|共3页
作者
Zicheng Xiao; Yi Zhu; Yongge Wei; Yuan Wang;
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正文语种 eng
中图分类无机化学;
关键词
Polyoxometalates; Organoimido derivatives; DCC; C-H...O hydrogen bond; Crystal data;

机译：多金属氧酸盐;有机亚氨基衍生物;DCC;C-H ... O氢键;晶体数据;

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1. Synthesis and characteristic of a new arylimido derivative of hexamolybdate with remote strong electro-donating group (Bu_4N)_2[Mo_6O_(18)NC_6H_4N(CH_3)_2-p] [J] . Zicheng Xiao, Yi Zhu, Yongge Wei, Inorganic Chemistry Communications . 2006,第4期

机译：带有强力给电子基团（Bu_4N）_2 [Mo_6O_（18）NC_6H_4N（CH_3）_2-p]的六钼酸新芳酰胺基衍生物的合成与表征
2. A new class of functionalized polyoxometalates: synthesis, structure and preliminary antitumor activity studies of three arylimido substituted hexamolybdates bearing a strong electron-withdrawing nitro group, (Bu4N)2[Mo6O18([triple bond]NAr)] (Ar = 3-NO2-C6H4, 2-CH3-4-NO2-C6H3, 2-CH3-5-NO2-C6H3) [J] . Xue SJ, Chai A, Cai ZJ, Dalton transactions: An international journal of inorganic chemistry . 2008,第35期

机译：一类新的功能化多金属氧酸盐：带有强吸电子硝基（Bu4N）2 [Mo6O18（[triple bond] NAr）]（Ar = 3-NO2-的三种芳基酰亚胺取代的六钼酸盐的合成，结构和初步抗肿瘤活性的研究C6H4、2-CH3-4-NO2-C6H3、2-CH3-5-NO2-C6H3）
3. A Kinetically Controlled Trans Bifunctionalized Organoimido Derivative of the Lindqvist-Type Hexamolybdate:Synthesis,Spectroscopic Characterization,and Crystal Structure of (n-Bu_4N)_2{trans-[Mo_6O_(17)(NAr)_2]} (Ar=2,6-dimethylphenyl) [J] . Yun Xia, Yongge Wei, Yuan Wang, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2005,第26期

机译：Lindqvist型六钼酸盐的动力学控制的反式双功能有机亚氨基衍生物：（n-Bu_4N）_2 {trans- [Mo_6O_（17）（NAr）_2]}（Ar = 2,6-的合成，光谱表征和晶体结构二甲基苯基）

Synthesis and characteristic of a new arylimido derivative of hexamolybdate with remote strong electro-donating group (Bu_4N)_2[Mo_6O_(18)NC_6H_4N(CH_3)_2-p]

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