The hydrothermal synthesis and structure of a one-dimensional Fe(II)molybdophosphate

Yunshan Zhou; Lijuan Zhang; Xiaozeng You; Srinivasan Natarajan

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The hydrothermal synthesis and structure of a one-dimensional Fe(II)molybdophosphate

机译：一维Fe（II）钼磷酸盐的水热合成和结构

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A new one-dimensional Fe(II)molybdophosphate of the formula, [(C_10H_8N_2)N_2]_2[Fe_4~9II)Mo_12~(V)(HPO_4)_6(PO_4)_2(H_2O)_8(OH)_6O_24]·8H_2O, (1), has been synthesized by employing hydrothermal methods and characterized by single crystal X-ray diffraction. The structure consists of a network of MO_6 (M = Fe, Mo) octahedra and (H)PO_4 tetrahedra linked thorugh their vertices. The connectivity between the polyhedral units gives rise to one-dimensional chains with eight-membered apertures. The hydrogen bonded interactions between the chains form pseudo two-dimensional layers. Extensive hydrogen bonding also exists between the amine molecule, 4,4'-bipyridine, water molecule and framework oxygen atoms. Crystal data for 1: monoclinic, space group = P2_1 (no. 4), a = 12.549(3) (A), b = 23.496(5), (A), c = 14.551 (3) (A), #beta# = 114.87(3) deg, V = 3892.5(15)A, and Z = 2.

机译：一种新的一维Fe（II）钼磷酸盐，其化学式为[（C_10H_8N_2）N_2] _2 [Fe_4〜9II）Mo_12〜（V）（HPO_4）_6（PO_4）_2（H_2O）_8（OH）_6O_24]·8H_2O ，（1），已通过水热法合成，并通过单晶X射线衍射表征。该结构由MO_6（M = Fe，Mo）八面体和（H）PO_4四面体连接的顶点组成的网络。多面体单元之间的连通性产生具有八元孔径的一维链。链之间的氢键相互作用形成伪二维层。胺分子，4,4'-联吡啶，水分子和骨架氧原子之间也存在广泛的氢键。 1的晶体数据：单斜晶，空间群= P2_1（编号4），a = 12.549（3）（A），b = 23.496（5），（A），c = 14.551（3）（A），#beta ＃= 114.87（3）度，V = 3892.5（15）A，Z = 2。

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来源
《Inorganic Chemistry Communications》 |2001年第12期|共6页
作者
Yunshan Zhou; Lijuan Zhang; Xiaozeng You; Srinivasan Natarajan;
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正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
hydrothermal synthesis4aone-dimensional structure; Fe(II); phosphate; molecular structure;

机译：水热合成;四元结构;Fe（II）;磷酸盐;分子结构;

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The hydrothermal synthesis and structure of a one-dimensional Fe(II)molybdophosphate

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