Microwave-assisted synthesis of a neodymium trichloride complex with phenanthroline containing infinite chains, NdCl3(H2O)(phen)

Jerome Lhoste; Natacha Henry; Thierry Loiseau

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Microwave-assisted synthesis of a neodymium trichloride complex with phenanthroline containing infinite chains, NdCl3(H2O)(phen)

机译：微波合成含邻菲咯啉NdCl3（H2O）（phen）的邻菲咯啉的三氯化钕配合物

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The microwave-assisted solvothermal synthesis (180 °C, 1 h) of a mixture of neodymium chloride, 1-10-phenanthroline (phen) in ethanol gives rise to the crystallization of a new phase, NdCl3(H2O)(phen). Its crystal structure consists of eight-fold coordinated lanthanide atoms, (bicapped trigonal prism, NdN2Cl5(H2O)) linked to each other through μ2-chloro groups via edge-sharing connection mode in order to generate infinite ribbons. The cohesion of the three-dimensional structure is ensured through hydrogen bond interactions between terminal chloride and water groups from distinct chains, as well as π-π interactions between the central benzene ring of two phen ligands. The occurrence of such a chain-like compound, with Nd/phen ratio of 1, is unique in the series of lanthanide-phenanthroline complexes. This compound is obtained by using a microwave heating procedure, which selectively induces the formation of such 1D coordination polymer. Thermogravimetric and infrared analyses are also detailed.

机译：微波辅助溶剂热合成氯化钕，1-10-邻菲咯啉（phen）在乙醇中的混合物产生新相NdCl3（H2O）（phen）的结晶。它的晶体结构由八倍配位的镧系元素原子（二阶三角棱镜，NdN2Cl5（H2O））通过μ2-氯基团通过边共享连接方式相互连接，从而生成无限的带。通过末端氯和来自不同链的水基团之间的氢键相互作用，以及两个phen配体的中心苯环之间的π-π相互作用，确保了三维结构的凝聚力。 Nd / phen比率为1的这种链状化合物的出现在一系列镧系元素-菲咯啉配合物中是独特的。通过使用微波加热程序获得该化合物，该程序选择性地诱导这种一维配位聚合物的形成。还详细介绍了热重分析和红外分析。

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《Inorganic Chemistry Communications》 |2011年第9期|共3页
作者
Jerome Lhoste; Natacha Henry; Thierry Loiseau;
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正文语种 eng
中图分类无机化学;
关键词
1D coordination polymer; Lanthanide chloride; 1; 10-phenanthroline; Microwave solvothermal synthesis; Single-crystal; X-ray diffraction; Thermogravimetric analysis;

机译：一维配位聚合物;氯化镧;1;10-菲咯啉;微波溶剂热合成;单晶;X射线衍射;热重分析;

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1. Microwave-assisted synthesis of a neodymium trichloride complex with phenanthroline containing infinite chains, NdCl3(H2O)(phen) [J] . Jerome Lhoste, Natacha Henry, Thierry Loiseau Inorganic Chemistry Communications . 2011,第9期

机译：微波合成含邻菲咯啉NdCl3（H2O）（phen）的邻菲咯啉的三氯化钕配合物
2. Synthesis and catalytic activity of manganese(II) complexes of pentanedioic acid; X-ray crystal structure of [Mn(phen)(2)(H2O)(2)][Mn(O2C(CH2)(3)CO2)(phen)(2)H2O](O2C(CH2)(3)CO2)cente r dot 12H(2)O (phen = 1,10-phenanthroline) [J] . Geraghty M., Casey MT., Curran M., Inorganica Chimica Acta . 1998,第2期

机译：戊二酸锰（Ⅱ）配合物的合成及催化活性[Mn（phen）（2）（H2O）（2）] [Mn（O2C（CH2）（3）CO2）（phen）（2）H2O]（O2C（CH2）（3）CO2的X射线晶体结构中心r点12H（2）O（phen = 1,10-菲咯啉）
3. 1D supramolecular double-chains based on pi-pi stacking interactions: Synthesis and crystal structure of [Cu(phen)(C10H16O4)]center dot 3 H2O with phen=1,10-phenanthroline [J] . Zheng YQ., Lin JL., Sun J. Zeitschrift fur Anorganische und Allgemeine Chemie . 2000,第6期

机译：基于pi-pi堆积相互作用的一维超分子双链：[phen（1,10-phenothroline）] [Cu（phen）（C10H16O4）]中心点3 H2O的合成和晶体结构
4. Hydrothermal Synthesis and Characterization of the Coordination Polymers with bta =Benzene-1,2,4,5- tetracarboxylate as Bridging Ligand: {Cu(phen)(μ4-bta)1/2· (H2O)}n(phen= 1,10-phenanthroline) [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：以bta =苯-1,2,4,5-四羧酸苯酯为桥联配体的水热合成和表征：{Cu（phen）（μ4-bta）1/2·（H2O）} n（phen = 1,10-菲咯啉
5. Markov chains, game theory, and infinite programming: Three paradigms for optimization of complex systems. [D] . Ghate, Archis Vijay. 2006

机译：马尔可夫链，博弈论和无限编程：优化复杂系统的三种范例。
6. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of Mn(ph)(Phen)2(H2O)· 4H2O Mn(Phen)2(H2O)22(Isoph)2(Phen)· 12H2O and {Mn(Isoph)(bipy)4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 110-Phenanthroline; bipy = 22-Bipyridine) [O] . Michael Devereux, Malachy McCann, Vanessa Leon, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：Mn（ph）（Phen）2（H2O）·4H2OMn（Phen）2（H2O）2 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{Mn（Isoph）（bipy） 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 110-邻菲咯啉; bipy = 22 -联吡啶）
7. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of [Mn(ph)(Phen)2(H2O)]· 4H2O, [Mn(Phen)2(H2O)2]2(Isoph)2(Phen)· 12H2O and {[Mn(Isoph)(bipy)]4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 1,10-Phenanthroline; bipy = 2,2-Bipyridine) [O] . Devereux, Michael, McCann, Malachy, Leon, Vanessa, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：[Mn（ph）（Phen）2（H2O）]·4H2O，[Mn（Phen）2（H2O）2] 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{[Mn（Isoph）（bipy）] 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 1,10-邻菲咯啉; bipy = 2,2 -联吡啶）

Microwave-assisted synthesis of a neodymium trichloride complex with phenanthroline containing infinite chains, NdCl3(H2O)(phen)

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