A bimetallic Co~(II)-Dy~(III) complex bridged by oxydiacetate ligand: Synthesis, structure, magnetic, spectral and TG properties of {[DyCo(oda)3]4[Co(H2O)6]2·6H2O}_n

Jun-Xia Li; Zhong-Xiang Du; Bao-Lin Zhu

首页> 外文期刊>Inorganic Chemistry Communications >A bimetallic Co~(II)-Dy~(III) complex bridged by oxydiacetate ligand: Synthesis, structure, magnetic, spectral and TG properties of {[DyCo(oda)3]4[Co(H2O)6]2·6H2O}_n

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A bimetallic Co~(II)-Dy~(III) complex bridged by oxydiacetate ligand: Synthesis, structure, magnetic, spectral and TG properties of {[DyCo(oda)3]4[Co(H2O)6]2·6H2O}_n

机译：由双氧乙酸配体桥接的双金属Co〜（II）-Dy〜（III）配合物：{[DyCo（oda）3] 4 [Co（H2O）6] 2·6H2O}的合成，结构，磁性，光谱和TG特性_n

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A novel 3d-4f heteronuclear coordination polymer containing cobalt and dysprosium, ([DyCo(oda)3]4{Co (H2O)6]2-6H2O}_n (1) (H2oda = oxydiacetic acid), has been synthesized and characterized by X-ray crystal diffraction, magnetic analysis, fluorescence and EPR spectrum as well as TGA studies. The single-crystal analysis shows that compound 1 displays unique hexadecagonal and octagonal channel structure. The photoluminescent spectrum of 1 indicates that the emissions come from intraligand π-π* transitions. Temperature-dependent magnetic susceptibilities, EPR and TG properties for 1 also have been discussed.

机译：合成并表征了一种新型的含钴和co的3d-4f杂核配位聚合物（[DyCo（oda）3] 4 {Co（H2O）6] 2-6H2O} _n（1）（H2oda =氧二乙酸） X射线晶体衍射，磁分析，荧光和EPR光谱以及TGA研究。单晶分析表明化合物1显示出独特的六边形和八边形通道结构。1的光致发光光谱表明其发射来自配体π- π*跃迁还讨论了1的温度依赖性磁化率，EPR和TG特性。

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《Inorganic Chemistry Communications》 |2011年第4期|共4页
作者
Jun-Xia Li; Zhong-Xiang Du; Bao-Lin Zhu;
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正文语种 eng
中图分类无机化学;
关键词
Oxydiacetic acid; Cobalt-dysprosium polymer; Fluorescence; EPR; Magnetic properties; TGA;

机译：氧二乙酸;钴-聚合物;荧光;EPR;磁性能;TGA;

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1. A bimetallic Co~(II)-Dy~(III) complex bridged by oxydiacetate ligand: Synthesis, structure, magnetic, spectral and TG properties of {[DyCo(oda)3]4[Co(H2O)6]2·6H2O}_n [J] . Jun-Xia Li, Zhong-Xiang Du, Bao-Lin Zhu Inorganic Chemistry Communications . 2011,第4期

机译：由双氧乙酸配体桥接的双金属Co〜（II）-Dy〜（III）配合物：{[DyCo（oda）3] 4 [Co（H2O）6] 2·6H2O}的合成，结构，磁性，光谱和TG特性_n
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A bimetallic Co~(II)-Dy~(III) complex bridged by oxydiacetate ligand: Synthesis, structure, magnetic, spectral and TG properties of {[DyCo(oda)3]4[Co(H2O)6]2·6H2O}_n

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