The preparation and molecular structure of the first primary ferrocenylphosphine complex of tungsten(II), [WI_2(CO)_3(FcCH_2PH_2)_2](Fc = Fe(#eta#~5-C_5H_5)(#eta#~5-C_5H_4)]

Rene Sommer; Peter Lonnecke; Paul K.Baker; Evamarie Hey-Hawkins

首页> 外文期刊>Inorganic Chemistry Communications >The preparation and molecular structure of the first primary ferrocenylphosphine complex of tungsten(II), [WI_2(CO)_3(FcCH_2PH_2)_2](Fc = Fe(#eta#~5-C_5H_5)(#eta#~5-C_5H_4)]

【24h】

The preparation and molecular structure of the first primary ferrocenylphosphine complex of tungsten(II), [WI_2(CO)_3(FcCH_2PH_2)_2](Fc = Fe(#eta#~5-C_5H_5)(#eta#~5-C_5H_4)]

机译：钨（II）[WI_2（CO）_3（FcCH_2PH_2）_2]（Fc = Fe（＃eta＃〜5-C_5H_5）（＃eta＃〜5-C_5H_4）的第一一级二茂铁基膦配合物的制备和分子结构]

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Reaction of [WI_2(CO)_3(NCMe)_2] with two equivalents of FcCH_2PH_2 (Fc = Fe(#eta#~5-C_5H_5)(#eta#~5-C_5H_4)] in CH_2Cl_2 at room temperature gave [WI_2(CO)_3(FcCH_2PH_2)_2] (1) in 94% yield which was crystallographically charactrised. This is the first primary ferrocenylphosphine complex of tungsten(II) and has a distorted capped octahedral structure, with trans-phosphine ligands and a carbonyl group that caps a triangular face formed by two carbonyl and one phosphine ligands.

机译：[WI_2（CO）_3（NCMe）_2]与两当量的FcCH_2PH_2（Fc = Fe（＃eta＃〜5-C_5H_5）（＃eta＃〜5-C_5H_4）]在室温下于CH_2Cl_2中反应，得到[WI_2（（CO）_3（FcCH_2PH_2）_2]（1）的晶体结构特征为收率94％，这是钨（II）的第一个一级二茂铁基膦配合物，具有扭曲的封端八面体结构，带有反式膦配体和一个羰基基团覆盖由两个羰基和一个膦配体形成的三角形面。

著录项

来源
《Inorganic Chemistry Communications》 |2002年第2期|共4页
作者
Rene Sommer; Peter Lonnecke; Paul K.Baker; Evamarie Hey-Hawkins;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
crystal structure; seven-coordinate; tungsten complex; primary ferrocenylphosphine; carbonyl; iodo ligand;

机译：晶体结构;七配位;钨配合物;初级二茂铁膦;羰基;碘配体;

相似文献

外文文献
中文文献
专利

1. The preparation and molecular structure of the first primary ferrocenylphosphine complex of tungsten(II), [WI_2(CO)_3(FcCH_2PH_2)_2](Fc = Fe(#eta#~5-C_5H_5)(#eta#~5-C_5H_4)] [J] . Rene Sommer, Peter Lonnecke, Paul K.Baker, Inorganic Chemistry Communications . 2002,第2期

机译：钨（II）[WI_2（CO）_3（FcCH_2PH_2）_2]（Fc = Fe（＃eta＃〜5-C_5H_5）（＃eta＃〜5-C_5H_4）的第一一级二茂铁基膦配合物的制备和分子结构]
2. Primary and Secondary Ferrocenylphosphine Complexes of Molybdenum(II) and Tungsten(II),[MI_2(CO)_(3-n)(PH_2R)2+n] [M=Mo,W; R=Fc,FcCH_2;Fc=Fe(eta~5-C_5H_5)(eta~5-C_5H_4); n=0,1],[MI_2(CO)_3{PH(CH_2Fc)_2}_2],and [WI_2(CO)_3(NCMe){PH(CH_2Fc)_2}]: Prepar [J] . Rene Sommer, Peter Lonnecke, Joachim Reinhold, Organometallics . 2005,第22期

机译：钼（II）和钨（II），[MI_2（CO）_（3-n）（PH_2R）2 + n]的伯和仲二茂铁膦配合物[M = Mo，W; R = Fc，FcCH_2; Fc = Fe（eta〜5-C_5H_5）（eta〜5-C_5H_4）; n = 0,1]，[MI_2（CO）_3 {PH（CH_2Fc）_2} _2]和[WI_2（CO）_3（NCMe）{PH（CH_2Fc）_2}]：准备
3. Photo-assisted preparation of double isocyanide insertion complexes of #eta#~5-cyclopentadienyliron(II) bearing only isocyanide: the molecular structure of (#eta#~5-C_5H_5)Fe(XylNC)_2[C(=NXyl)C(=NXyl)CH_3(XylNC = 2,6-Me_2C_6H_3NC) [J] . Yasuhiro Yamamoto, Masayuki Tsuji, Toshiaki Igoshi Inorganica Chimica Acta . 1999,第2期

机译：光辅助制备仅带有异氰酸酯的＃eta＃〜5-环戊二烯铁（II）的双异氰酸酯插入配合物：（＃eta＃〜5-C_5H_5）Fe（XylNC）_2 [C（= NXyl）C（ = NXyl）CH_3（XylNC = 2,6-Me_2C_6H_3NC）
4. Preparation and Characterization of Stable Molecular Glasses of Europium(III) Acyl-Alaninate Complexes [C] . Naren Gerile, H. Alata, Tian Xiao, International Conference on Materials Science . 2018

机译：铕（III）稳定分子玻璃的制备与表征酰基 - 丙氨酸酯复合物
5. Preparation and physical properties of molecular materials based on metalloporphyrazines (M = cobalt, nickel, copper, zinc) and paddlewheel complexes (M = molybdenum, tungsten, ruthenium). [D] . Pate, Brian D. 2004

机译：基于金属卟啉（M =钴，镍，铜，锌）和桨轮配合物（M =钼，钨，钌）的分子材料的制备和物理性质。
6. A human CD4+ T-cell line expresses functional CD64 (Fc gamma RI) CD32 (Fc gamma RII) and CD16 (Fc gamma RIII) receptors but these do not enhance the infectivity of HIV-1-IgG complexes. [O] . L McLain, N J Dimmock 1997

机译：人CD4 + T细胞系表达功能性CD64（FcγRI）CD32（FcγRII）和CD16（FcγRIII）受体但这些受体不能增强HIV-1-IgG复合物的感染力。
7. Primary and Secondary Ferrocenylphosphine Complexes of Molybdenum(II) and Tungsten(II), MI2(CO)3-n(PH2R)2+n M = Mo, W; R = Fc, FcCH2; Fc = Fe(h5-C5H5)(h5-C5H4); n = 0, 1, MI2(CO)3{PH(CH2Fc)2}2, and WI2(CO)3(NCMe){PH(CH2Fc)2}: Preparation, Molecular Structure, Dynamic Behavior, Catalytic Properties, and Theoretical Calculations [O] . -1

机译：钼（II）和钨（II），MI2（CO）3-N（PH2R）2 + N M = MO，W;初级和仲二烯基膦络合物r = fc，fcch2; Fc = Fe（H5-C5H5）（H5-C5H4）; n = 0,1，Mi2（CO）3 {pH（CH2FC）2} 2，和Wi2（CO）3（NCME）{pH（CH2FC）2}：制备，分子结构，动态行为，催化性质和理论计算

The preparation and molecular structure of the first primary ferrocenylphosphine complex of tungsten(II), [WI_2(CO)_3(FcCH_2PH_2)_2](Fc = Fe(#eta#~5-C_5H_5)(#eta#~5-C_5H_4)]

摘要

著录项

相似文献

相关主题

期刊订阅