An aqua-adenine H-bonding interaction controlling the formation of the rare Zn(II)-N9(adenine) bond in crystal structure of diaqua(adenine)(iminodiacetato)zinc(II)

A.C.Morel; D.Choquesillo-Lazarte; C.Alarcon-Payer; J.M.Gonzalez-Perez; A.Castineiras; J.Niclos-Gutierrez

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An aqua-adenine H-bonding interaction controlling the formation of the rare Zn(II)-N9(adenine) bond in crystal structure of diaqua(adenine)(iminodiacetato)zinc(II)

机译：水-腺嘌呤的氢键相互作用控制二水（腺嘌呤）（亚氨基二乙酰基）锌（II）晶体结构中稀有Zn（II）-N9（腺嘌呤）键的形成

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A novel mixed-ligand zinc(II) complex with iminoidiacetato(2-) (IDA) and adenine (AdeH) ligands has been obtained.Its crystal consists of octaohedral molecules [Zn(IDA)(AdeH)(H_2O)_2] where the selective Zn-N9(AdeH) bond,involving the most basic N(AdeH) bond,involving the most basic N(AdeH) donor atom,occupies the trans position versus the Zn-N(IDA) bond.The Zn(II)-N9(AdeH) binding mode seems to be rare enough in comparison to those previously reported for Zn(II) and AdeH or a variety of related ligands.The chelate-nucleobase recognition process

机译：获得了一种新型的具有亚氨基二乙酰基（2-）（IDA）和腺嘌呤（AdeH）配体的混合配体锌（II）配合物。其晶体由八面体分子[Zn（IDA）（AdeH）（H_2O）_2]组成。选择性的Zn-N9（AdeH）键，涉及最碱性的N（AdeH）键，涉及最碱性的N（AdeH）供体原子，相对于Zn-N（IDA）键占据反式位置.Zn（II）-与先前报道的Zn（II）和AdeH或各种相关配体相比，N9（AdeH）结合模式似乎非常罕见。

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来源
《Inorganic Chemistry Communications》 |2003年第11期|共4页
作者
A.C.Morel; D.Choquesillo-Lazarte; C.Alarcon-Payer; J.M.Gonzalez-Perez; A.Castineiras; J.Niclos-Gutierrez;
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正文语种 eng
中图分类无机化学;
关键词
crystal structure; adenine; iminodiacetate; Zinc(II); molecular recognition; H-bonding; inter-ligand interactions;

机译：晶体结构;腺嘌呤;亚氨基二乙酸酯;锌（II）;分子识别;H键;配体间相互作用;

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1. An aqua-adenine H-bonding interaction controlling the formation of the rare Zn(II)-N9(adenine) bond in crystal structure of diaqua(adenine)(iminodiacetato)zinc(II) [J] . A.C.Morel, D.Choquesillo-Lazarte, C.Alarcon-Payer, Inorganic Chemistry Communications . 2003,第11期

机译：水-腺嘌呤的氢键相互作用控制二水（腺嘌呤）（亚氨基二乙酰基）锌（II）晶体结构中稀有Zn（II）-N9（腺嘌呤）键的形成
2. Interligand interactions controlling the mu-N7,N9-metal bonding of adenine (AdeH) to the N-benzyliminodiacetato(2-) copper(II) chelate and promoting the N9 versus N3 tautomeric proton transfer: Molecular and crystal structure of [Cu-2(NBzIDA)(2)(H2O) [J] . Rojas-Gonzalez PX., Castineiras A., Gonzalez-Perez JM. Choquesillo-Lazarte D., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2002,第24期

机译：控制腺嘌呤（AdeH）与N-苄基亚氨基二乙酰基（2-）铜（II）螯合物的mu-N7，N9金属键的配位体相互作用并促进N9与N3互变异构质子转移：[Cu-2 （NBzIDA）（2）（H2O）
3. MIXED-LIGAND COPPER(II) COMPLEXES WITH N-METHYL DERIVATIVES OF IMINODIACETATO OR IMIDAZOLE - CRYSTAL STRUCTURES OF (N-METHYL-IMINODIACETATO)(IMIDAZOLE) COPPER(II), [CU(MIDA)(IMH)] AND DIAQUA(IMINODIACETATO)(N-METHYL-IMIDAZOLE)COPPER(II) MONOHYDRATE, [J] . Campos AC., Perez JMG., Gutierrez JN., Inorganica Chimica Acta . 1996,第2期

机译：含亚氨基二乙酰或咪唑的N-甲基衍生物的混合配体铜（II）络合物-（N-甲基-亚氨基二乙酰）（咪唑）的铜（II），[Cu（MIDA）（IMH）]和对苯二甲酰亚胺的晶体结构（N-甲基-咪唑）一水合铜（II），
4. Differential Raman spectroscopic study of the interaction of nickel (II) cation with adenine nucleotides [C] . Peter Mojzes Intermational conference on laser applications in life sciences . 1994

机译：含镍（II）阳离子与腺嘌呤核苷酸相互作用的差分拉曼光谱研究
5. I. Development of a novel nitrogen protection group: Tsoc (triisopropylsilyloxycarbonyl). II. Controlling atropisomerism using a chiral tether in biaryl bond formation. III. Advances in copper hydride chemistry. [D] . Papa, Patrick William. 2002

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6. Supramolecular Assembly of a Zn(II)-Based 1D Coordination Polymerthrough Hydrogen Bonding and π···π Interactions:Crystal Structure and Device Applications [O] . Basudeb Dutta, Arka Dey, Suvendu Maity, 2018

机译：Zn（II）基一维配位聚合物的超分子组装通过氢键和π···π相互作用：晶体结构与器件应用
7. Elementary Patterns in Protein-Nucleic Acid Interactions. III. Crystal Structure of Adenine: Phthalic Acid (3:1) Complex Hexahydrate [O] . Akio Takenaka, Yoshio Sasada 1982

机译：蛋白质 - 核酸相互作用中的基本模式。 III。腺嘌呤的晶体结构：邻苯二甲酸（3：1）络合物六水合物

An aqua-adenine H-bonding interaction controlling the formation of the rare Zn(II)-N9(adenine) bond in crystal structure of diaqua(adenine)(iminodiacetato)zinc(II)

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