N_(10) deca-coordinated environment for a Ba(II) complex with tetrapyridyl pendant-armed azamacrocyclic ligand

Luis Botana; Rufina Bastida; Alejandro Macias

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N_(10) deca-coordinated environment for a Ba(II) complex with tetrapyridyl pendant-armed azamacrocyclic ligand

机译：N_（10）十配位环境的Ba（II）配合物与四吡啶悬挂侧氮杂大环配体

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An interesting Ba(II) complex with a tetrapyridyl pendant-armed azamacrocyclic is reported. The X-ray crystal structure shows the metal ion coordinated by the 10 nitrogen donor atoms from the ligand, six of them from the macrocyclic framework and the remaining four nitrogen atoms from the pyridinic pendant-arms. The coordination geometry around the metal can be considered as a distorted bicapped cube. To the best of our knowledge, only two N_(10)-coordinated Ba(II) complexes have been previously reported, and only one of them is a macrocyclic Ba(II) complex.

机译：报道了一种有趣的Ba（II）配合物，该配合物带有四吡啶基侧链武装的氮杂大环。 X射线晶体结构显示金属离子由配体中的10个氮供体原子配位，其中6个来自大环骨架，其余的4个氮原子来自吡啶侧链。金属周围的配位几何可以被认为是扭曲的二等边立方体。据我们所知，以前仅报道过两个N_（10）配位的Ba（II）配合物，其中只有一个是大环Ba（II）配合物。

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《Inorganic Chemistry Communications》 |2009年第3期|共3页
作者
Luis Botana; Rufina Bastida; Alejandro Macias;
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正文语种 eng
中图分类无机化学;
关键词
Barium(II); Azamacrocyclic ligand; Pendat-arms; X-ray crystal structure;

机译：钡（2）;氮杂大环配体;吊臂;10射线晶体结构;

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1. N_(10) deca-coordinated environment for a Ba(II) complex with tetrapyridyl pendant-armed azamacrocyclic ligand [J] . Luis Botana, Rufina Bastida, Alejandro Macias Inorganic Chemistry Communications . 2009,第3期

机译：N_（10）十配位环境的Ba（II）配合物与四吡啶悬挂侧氮杂大环配体
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N_(10) deca-coordinated environment for a Ba(II) complex with tetrapyridyl pendant-armed azamacrocyclic ligand

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