A novel three-dimensional cadmium(II) coordination polymer constructed from dinuclear molecular building block, syntheses, structure and photoluminescence property

Dong Xie; Junwei Ye; Zhao Liu

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A novel three-dimensional cadmium(II) coordination polymer constructed from dinuclear molecular building block, syntheses, structure and photoluminescence property

机译：由双核分子结构单元，合成，结构和光致发光性质构建的新型三维镉（II）配位聚合物

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A novel cadmium(II) coordination polymer, [Cd2(pzdc)2(4,4'-bpy)2]·4H2O (1) (H2pzdc = pyrazine-2,3-dicarboxylic acid; 4,4'-bpy = 4,4'-bipyridine), has been synthesized by hydrothermal reaction of Cd(0AC)2, H2pzdc and 4,4'-bpy. Single-crystal X-ray diffraction analysis reveals that 1 constructed from dinuclear building blocks has a three-dimensional (3-D) structure with rob topology. Fluorescent measurement of 1 exhibits strong blue-green emission in the solid state at room temperature, and its framework possess remarkable thermal stability.

机译：新型镉（II）配位聚合物[Cd2（pzdc）2（4,4'-bpy）2]·4H2O（1）（H2pzdc =吡嗪-2,3-二羧酸; 4,4'-bpy = 4 （4'-联吡啶），是通过Cd（0AC）2，H2pzdc和4,4'-bpy的水热反应合成的。单晶X射线衍射分析显示，由双核结构单元构建的1具有三维结构（3-D），具有rob拓扑。 1的荧光测量在室温下在固态下显示出强烈的蓝绿色发射，并且其骨架具有出色的热稳定性。

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来源
《Inorganic Chemistry Communications》 |2009年第2期|共4页
作者
Dong Xie; Junwei Ye; Zhao Liu;
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正文语种 eng
中图分类无机化学;
关键词
Coordination polymer; Cadmium(II); Dinuclear building block; Photoluminescence;

机译：配位聚合物;镉（II）;双核结构单元;光致发光;

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专利

1. A novel three-dimensional cadmium(II) coordination polymer constructed from dinuclear molecular building block, syntheses, structure and photoluminescence property [J] . Dong Xie, Junwei Ye, Zhao Liu Inorganic Chemistry Communications . 2009,第2期

机译：由双核分子结构单元，合成，结构和光致发光性质构建的新型三维镉（II）配位聚合物
2. Cadmium(II) and zinc(II) coordination polymers with mixed building blocks of benzenedicarboxyl and 2,5-bipyridyl-1,3,4-oxadiazole: Syntheses, crystal structures, and properties [J] . Chen J., Liu S.-Y., Li C.-P. Inorganica Chimica Acta . 2011,第1期

机译：具有混合结构单元的苯二羧基和2,5-联吡啶-1,3,4-恶二唑的镉（II）和锌（II）配位聚合物：合成，晶体结构和性质
3. Three-dimensional Ln(III)-Mn(II) metal organic frameworks constructed from Rod-shaped molecular building blocks: Syntheses, structures and magnetic properties [J] . Qjanqian Wang, Junwei Ye, Ge Tian Inorganic Chemistry Communications . 2011,第6期

机译：由棒状分子构件构建的三维Ln（III）-Mn（II）金属有机骨架：合成，结构和磁性
4. A Zigzag Chain Cd (II) Coordination Polymer Based on 2,4-Dinitro-benzoic Acid Ligand: Syntheses, Structure and Photoluminescence [C] . Hui Bai, Hong Gao, Ming Hu International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials . 2014

机译：基于2,4-二硝基苯甲酸配体的Z字形链CD（II）配位聚合物：合成，结构和光致发光
5. Octahedral metal clusters as molecular building blocks of coordination polymers: Synthesis, characterization, and study of their host-guest interactions. [D] . Chen, Lei. 2011

机译：八面体金属簇作为配位聚合物的分子构建基块：合成，表征和研究其主客体相互作用。
6. Various Structural Types of Cyanide-Bridged FeIII–MnIII Bimetallic Coordination Polymers (CPs) and Polynuclear Clusters Based-on A New mer-Tricyanoiron(III)Building Block: Synthesis Crystal Structures and Magnetic Properties [O] . Wenlong Lan, Xiaoyun Hao, Yong Dou, 2019

机译：基于新的三氰基铁（III）构建基的氰化桥联的FeIII-MnIII双金属配位聚合物（CP）和多核簇的各种结构类型：合成晶体结构和磁性
7. Synthesis, Structure, and Luminescent Properties of Rare Earth Coordination Polymers Constructed from Paddle-Wheel Building Blocks [O] . -1

机译：稀土配位聚合物的合成，结构和发光性能由桨轮构建块构成的稀土配位聚合物

A novel three-dimensional cadmium(II) coordination polymer constructed from dinuclear molecular building block, syntheses, structure and photoluminescence property

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