An intertwined double chain constructed by [SiMo_(12)O_(40)]~(4-) clusters and unusual [Cu2(DF)2H2O] dimers

Hai-jun Pang; Jing-quan Sha; Jun Peng

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An intertwined double chain constructed by [SiMo_(12)O_(40)]~(4-) clusters and unusual [Cu2(DF)2H2O] dimers

机译：由[SiMo_（12）O_（40）]〜（4-）簇和不寻常的[Cu2（DF）2H2O]二聚体构成的缠结双链

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A new compound, {[Cu2(DF)2H2O]2SiMo_(12)O_(40)} (1) (DF = 4,5-diazafluoren-9-one), has been hydrother-mally synthesized and characterized by routine methods and single crystal X-ray diffraction. In 1, all the DF only adopt the unusual bidentate coordination mode for the first time coordinating to Cu atoms to form copper-dimers which link [SiMo_(12)O_(40)]~(4-) clusters obtaining an intertwined double chain. Furthermore, the luminescent and electrochemical properties of the title compound have been studied.

机译：一种新的化合物{[Cu2（DF）2H2O] 2SiMo_（12）O_（40）}（1）（DF = 4,5-二氮杂芴-9-one）已通过水热合成并通过常规方法表征单晶X射线衍射。在图1中，所有DF都仅首次采用异常的双齿配位模式与Cu原子配位以形成铜二聚体，这些铜二聚体将[SiMo_（12）O_（40）]〜（4-）团簇链接在一起，形成双链缠绕。此外，已经研究了标题化合物的发光和电化学性质。

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《Inorganic Chemistry Communications》 |2009年第8期|共4页
作者
Hai-jun Pang; Jing-quan Sha; Jun Peng;
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正文语种 eng
中图分类化学工业;
关键词
4; 5-Diazafluoren-9-one; Bidentate coordination mode; Polyoxometaiates; Luminescent and electrochemical properties;

机译：4;5-二氮杂芴-9-一;二元配位模式;多甲酸酯;发光和电化学性质;

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1. An intertwined double chain constructed by [SiMo_(12)O_(40)]~(4-) clusters and unusual [Cu2(DF)2H2O] dimers [J] . Hai-jun Pang, Jing-quan Sha, Jun Peng Inorganic Chemistry Communications . 2009,第8期

机译：由[SiMo_（12）O_（40）]〜（4-）簇和不寻常的[Cu2（DF）2H2O]二聚体构成的缠结双链
2. Cation effectsX on the voltammetric behavior of #alpha#-Keggin-type [SiMo_(12)O_(40)]~(4-) and [PMo_(12)O_(40)]~(3-) complexes in CH_3COCH_3 and CH_3CN [J] . Sadayuki Himeno, Masayo Takamoto, Tadaharu Ueda Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2000,第1期

机译：阳离子效应X对CH_3COCH_3和CH_3CN中＃alpha＃-Keggin型[SiMo_（12）O_（40）]〜（4-）和[PMo_（12）O_（40）]〜（3-）配合物的伏安行为的影响
3. Synthesis, crystal structure and characterization of a series of complexes constructed from coordinated Lanthanides(III) and the heteropolyanion [SiMo_(12)O_(40)]~(4-) [J] . QIU-XIA HAN, JING-PING WANG, JING-YANG NIU Journal of Coordination Chemistry . 2007,第12a14期

机译：由配位镧系元素（III）和杂多阴离子[SiMo_（12）O_（40）]〜（4-）构成的一系列配合物的合成，晶体结构和表征
4. COMPARISON OF THE BEHAVIOURS OF GaAs AND InP IN THE PRESENCE OF SiMo_(12)O_(40)~(4-) IN ACIDIC SOLUTION [C] . Anne Quennoy, Amaud Etcheberry, Catherine ebiemme-Chouvy International Symposium on State-of-the-Art Program on Compound Semiconductors(SOTAPOCS XXXVII) and Narrow Bandgap Optoelectronic Materials and Devices and Electrochemical Society Meeting; 20021020-20021025; Salt Lake City,UT; US . 2002

机译：酸性溶液中存在SiMo_（12）O_（40）〜（4-）时GaAs和InP行为的比较
5. Tetrahydroxy-p-benzoquinone as a Source of Polydentate O-Donor Ligands. Synthesis, Crystal Structure, and Magnetic Properties of the Cu(bpy)(dhmal)2 Dimer and the Two-Dimensional {SiW12O40}{Cu2(bpy)2(H2O)(ox)}216H2O Inorganic-Metalorganic Hybrid [O] . -1

机译：四羟基-P-苯并醌作为多晶体O-供体配体的来源。 Cu（BPY）（DHMAL） 2二聚体和二维{SiW12O40} {Cu2（BPY）2（H2O）（H 2 O）（OX）} 2 16H2O无机 - 金属有机杂种的合成，晶体结构和磁性

An intertwined double chain constructed by [SiMo_(12)O_(40)]~(4-) clusters and unusual [Cu2(DF)2H2O] dimers

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