Synthesis, spectral characterization, properties and structure of dinuclear rhenium complex containing bis[4-(2-pyridylmethyleneamino)phenyl]methane pgand

Saeed Dehghanpour; Mehdi Khalaj; Ali Mahmoudi

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Synthesis, spectral characterization, properties and structure of dinuclear rhenium complex containing bis[4-(2-pyridylmethyleneamino)phenyl]methane pgand

机译：含双[4-（2-吡啶基亚甲基氨基）苯基]甲烷pgand的双核rh配合物的合成，光谱表征，性质和结构

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摘要

The synthesis, characterization, properties and crystal structure of {(bis[4-(2-pyridylmethyleneamino)-phenyl]methane)[Re(CO)3Br]2} complex are reported. The ~1H NMR data for this complex shows downfield shift of the bis-diimine ligand protons upon coordination to the Re center. The molecular structure of the dinuclear rhenium(I) complex exhibits distorted octahedral geometries around the each metal center with one Br and facial arrangement of three CO and a cis-bonded diimine ligands. The bis-diimine ligand, twists via a half-turn around the metal-metal axis. Electrochemical investigation reveals two oxidation waves and two irreversible reduction waves.

机译：报道了{（双[4-（2-吡啶基亚甲基氨基）-苯基]甲烷）[Re（CO）3Br] 2}配合物的合成，表征，性质和晶体结构。该络合物的〜1H NMR数据显示，与Re中心配位后，双二亚胺配体质子的场下偏移。双核rh（I）配合物的分子结构在每个金属中心周围呈现扭曲的八面体几何形状，具有一个Br和三个CO和一个顺式键合的二亚胺配体的面排列。双二亚胺配体绕金属-金属轴旋转半圈。电化学研究显示出两个氧化波和两个不可逆还原波。

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来源
《Inorganic Chemistry Communications》 |2009年第3期|共3页
作者
Saeed Dehghanpour; Mehdi Khalaj; Ali Mahmoudi;
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正文语种 eng
中图分类无机化学;
关键词
Rhenium complex; Tetradentate diimine ligand; X-ray crystallography; Electrochemistry;

机译：hen配合物四齿二亚胺配体X射线晶体学电化学;

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1. Synthesis, spectral characterization, properties and structure of dinuclear rhenium complex containing bis[4-(2-pyridylmethyleneamino)phenyl]methane pgand [J] . Saeed Dehghanpour, Mehdi Khalaj, Ali Mahmoudi Inorganic Chemistry Communications . 2009,第3期

机译：含双[4-（2-吡啶基亚甲基氨基）苯基]甲烷pgand的双核rh配合物的合成，光谱表征，性质和结构
2. Tricarbonyl rhenium complexes of bis(pyrazol-1-yl)methane and bis(3,5-dimethylpyrazol-1-yl)methane - Synthesis, spectroscopic characterization, X-ray structure and DFT calculations [J] . Machura B, Kruszynski R, Jaworska M, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2008,第6期

机译：双（吡唑-1-基）甲烷和双（3,5-二甲基吡唑-1-基）甲烷的三羰基rh配合物-合成，光谱表征，X射线结构和DFT计算
3. Synthesis and structures of dinuclear Rh-III and Ir-III complexes supported by a tetraphosphine, meso- or rac-bis {[(diphenylphosphinomethyl)phenyl]phosphino]}methane [J] . Tanase Tomoaki, Yoshii Akiko, Otaki Risa, Journal of Organometallic Chemistry . 2015,第Null期

机译：四膦，内消旋或外消旋双{[（（二苯基膦基甲基）苯基]膦基]}甲烷负载的双核Rh-III和Ir-III配合物的合成和结构
4. Synthesis and Characterization of Polyimides from Bis(3-aminophenyl)-4-(1- adamantyl) Phenoxy Phenyl-phosphine Oxide (mDAATPPO) [C] . S. M. Kwak, J. H. Kim, Y. U. Bae PMSE Symposia . 2005

机译：来自双（3-氨基苯基）-4-（1-酰胺基）苯基磷酸氧化膦（MDAATPPO）的聚酰亚胺的合成与表征
5. Synthesis, structural variations and trends in the properties of unique dinuclear and polynuclear complexes of bis(pyrazolyl)methane ligands in solid state and solution. [D] . Pascui, Andrea Eva. 2013

机译：固态和溶液中双（吡唑基）甲烷配体独特的双核和多核配合物的合成，结构变化和性质趋势。
6. Synthesis and Characterization of Organosoluble Thermal Stable and Hydrophobic Polyimides Derived from 4-(4-(1-Pyrrolidinyl)phenyl)-26-bis(4-(4-aminophenoxy)phenyl)pyridine [O] . Xiaohua Huang, Beicai Chen, Mei Mei, 2017

机译：4-（4-（1-吡咯烷基）苯基）-26-双（4-（4-氨基苯氧基）苯基）吡啶衍生的有机可溶性热稳定和疏水性聚酰亚胺的合成和表征
7. Possible cobalt-cobalt bridging by a hemiacetal in the dinuclear cobalt complex bearing the ligand bis(3-(2-Pyridylmethyleneamino)phenyl) sulfone [O] . Armando M. Guidote, Tomoko Imajo, Yoshiro Masuyama 1970

机译：在携带配体双（3-（2-吡啶基甲基氨基）苯基）砜的亚核钴络合物中的半核钴桥中可能的钴 - 钴桥桥接
8. Bis (4-(3,4-dimethylene-pyrrolidyl)-phenyl) methane [R] . 1990

机译：双（4-（3,4-二甲基 - 吡咯烷酮） - 苯基）甲烷

Synthesis, spectral characterization, properties and structure of dinuclear rhenium complex containing bis[4-(2-pyridylmethyleneamino)phenyl]methane pgand

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