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首页> 外文期刊>Inorganic Chemistry Communications >Yeast alcohol dehydrogenase can be used as a supramolecular assembly agent for fabricating Ru(bpy)~(3+)-containing luminescent materials towards solid-state electrochemiluminescene detection application
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Yeast alcohol dehydrogenase can be used as a supramolecular assembly agent for fabricating Ru(bpy)~(3+)-containing luminescent materials towards solid-state electrochemiluminescene detection application

机译:酵母醇脱氢酶可用作超分子组装剂,用于制备含Ru(bpy)〜(3+)的发光材料,用于固态电化学发光检测应用

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摘要

In this communication I report on a solution-based assembly strategy for the preparation of Ru(bpy)_3~(2+)-containing luminescent materials with the use of yeast alcohol dehydrogenase (YADH) as a supramolecular assembly agent, involving the direct mix of concentrated Ru(bpy)3Cl2 and YADH aqueous solutions at room temperature. It is unexpectedly found that the resulting assemblies can form very stable film on bare electrode surfaces and at the same time exhibit excellent electrochemiluminescene (ECL) behaviors and therefore, provide us a novel kind of easily-immobilized luminescent materials for solid-state ECL detection in capillary electrophoresis (CE) or CE microchip.
机译:在本交流中,我报告了一种基于溶液的组装策略,该方法使用酵母醇脱氢酶(YADH)作为超分子组装剂,制备含Ru(bpy)_3〜(2+)的发光材料,涉及直接混合室温下浓缩浓Ru(bpy)3Cl2和YADH水溶液。出乎意料地发现,所得的组件可以在裸露的电极表面上形成非常稳定的膜,同时表现出出色的电化学发光(ECL)行为,因此,为我们提供了一种新型的易于固定的发光材料,用于固体ECL检测。毛细管电泳(CE)或CE微芯片。

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