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Solvothermal synthesis and characterization of a lithium coordination polymer possessing a highly stable 3D network structure

机译:溶剂热合成和表征具有高度稳定的3D网络结构的锂配位聚合物

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摘要

Solvothermal reaction of lithium perchlorate and 1,4-benzene dicarboxylic acid at 180 °C has resulted in a novel lithium coordination polymer Li2 (CO2-C6H4-CO2), which is characterized by single crystal X-ray diffraction analysis, X-ray powder diffraction analysis, elemental analysis, TGA/DTA and IR spectra. The compound shows a remarkable high thermal stability up to 530 °C, features a new 3D network containing two types of 6-membered ring and 18-membered dumbbell-like ring in view from different directions.
机译:高氯酸锂与1,4-苯二甲酸在180°C的溶剂热反应生成了新型的锂配位聚合物Li2(CO2-C6H4-CO2),其特征在于单晶X射线衍射分析,X射线粉末衍射分析,元素分析,TGA / DTA和红外光谱。该化合物在高达530°​​C的温度下显示出显着的高热稳定性,并具有新型3D网络,该网络包含从不同方向观察的两种类型的6元环和18元哑铃状环。

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