Helical silver(I) coordination polymer with oxazoline-containing ligand: Structure, non-linear and ferroelectric property

Yue Zhao; Li Luo; Chang Liu

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Helical silver(I) coordination polymer with oxazoline-containing ligand: Structure, non-linear and ferroelectric property

机译：含恶唑啉配体的螺旋银（I）配位聚合物：结构，非线性和铁电性能

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A new coordination polymer [Ag4(dob)4(BF4)4] (1) was synthesized by reaction of rigid ligand 1,3-di(2-oxazolinyl)benzene (dob) with silver(I) tetrafluoroborate and characterized by elemental analysis, single crystal X-ray diffraction and electrospray mass spectrometry. The complex has one-dimensional (1D) helical chain structure which is further linked together by Ag F and hydrogen bonding interactions to form a threedimensional (3D) supramolecular structure. Complex 1 crystallizes in the noncentrosymmetrical space group and shows second harmonic generation (SHG) and ferroelectric property.

机译：通过刚性配体1,3-二（2-恶唑啉基）苯（dob）与四氟硼酸银（I）的反应合成了一种新的配位聚合物[Ag4（dob）4（BF4）4]（1）。，单晶X射线衍射和电喷雾质谱。该配合物具有一维（1D）螺旋链结构，该结构通过Ag F和氢键相互作用进一步连接在一起，形成三维（3D）超分子结构。配合物1在非中心对称空间群中结晶，并显示出二次谐波（SHG）和铁电特性。

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《Inorganic Chemistry Communications》 |2011年第7期|共4页
作者
Yue Zhao; Li Luo; Chang Liu;
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正文语种 eng
中图分类无机化学;
关键词
Silver(I) complex; Helical chain; Noncentrosymmetrical space group; SHG; Ferroelectric property;

机译：银（I）配合物;螺旋链;非中心对称空间群;SHG;铁电性质;

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专利

1. Helical silver(I) coordination polymer with oxazoline-containing ligand: Structure, non-linear and ferroelectric property [J] . Yue Zhao, Li Luo, Chang Liu Inorganic Chemistry Communications . 2011,第7期

机译：含恶唑啉配体的螺旋银（I）配位聚合物：结构，非线性和铁电性能
2. Well-designed strategy to construct helical silver(I) coordination polymers from flexible unsymmetrical bis(pyridyl) ligands: Syntheses, structures, and properties [J] . Zhang Z.-Y., Deng Z.-P., Huo L.-H., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2013,第10期

机译：从柔性不对称双（吡啶基）配体构建螺旋银（I）配位聚合物的精心设计策略：合成，结构和性质
3. Synthesis, Structure, and Thermal Stability of Silver(I) Coordination Polymers with Bis(pyridyl) Ligands Linked by an Aromatic Sulfonamide: One-Dimensional-Straight Chain, One-Dimensional-Columnar with Helical Components, and Two-Dimensional-Layer Network Structures [J] . Kosuke Katagiri, Takahiro Sakai, Maiko Hishikawa, Crystal growth & design . 2014,第1期

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4. Lanthanide Coordination Polymers with Hexa-carboxylate Ligands Derived from Cyclotriphosphazene: Structures and Luminescent Properties [C] . F.Yu, S.J.Cai, H.P.Wang, Proceedings of the Sixth Asia-Europe symposium on processing and properties of reinforced polymers . 2013

机译：环三磷腈衍生的具有六羧酸根配体的镧系配位聚合物：结构和发光性能
5. Synthesis, Structure and Catalytic Application of Silver (I) Coordination Polymers Based on 1,2,4,5-Tetra(Isopropylthio)Benzene Ligand [D] . Kakumanu, Srinija. 2017

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6. Crystal structure of a helical silver(I) coordination polymer based on an unsymmetrical dipyridyl ligand: catena-polysilver(I)-μ-N-(pyridin-4-ylmethyl)pyridine-3-amine-κ2N:N′ tetrafluoridoborate methanol hemisolvate [O] . Suk-Hee Moon, Youngjin Kang, Ki-Min Park 2015

机译：基于不对称二吡啶基配体的螺旋银（I）配位聚合物的晶体结构：链状聚银（I）-μ-N-（吡啶-4-基甲基yl基）吡啶-3-胺-κ2N：N四氟硼硼酸甲醇半溶剂化物
7. Crystal structure of a helical silver(I) coordination polymer based on an unsymmetrical dipyridyl ligand: catena-poly[[silver(I)-μ-N-(pyridin-4-ylmethyl)pyridine-3-amine-κ2N:N′] tetrafluoridoborate methanol hemisolvate] [O] . Suk-Hee Moon, Youngjin Kang, Ki-Min Park 2015

机译：基于不对称二吡啶基配体的螺旋银（I）配位聚合物的晶体结构：catena-poly [[银（I）-μ-N-（吡啶-4-基甲基）吡啶-3-胺-κ2N：N']四氟硼酸盐甲醇半溶剂化物]

Helical silver(I) coordination polymer with oxazoline-containing ligand: Structure, non-linear and ferroelectric property

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