Unprecedented 5,5-connected (4~7 · 6~3) (4~8 · 6~2) structural topology: A lead biphosphonate with double layered structure

Shu-Fang Zhang; Zhi Liu; Xiao-Gang Yang

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Unprecedented 5,5-connected (4~7 · 6~3) (4~8 · 6~2) structural topology: A lead biphosphonate with double layered structure

机译：前所未有的5,5连接（4〜7·6〜3）（4〜8·6〜2）结构拓扑：双层结构的双膦酸铅

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摘要

A new lead(II) phosphonate, Pb[(PO3)2C(OH)CH3] · H2O (1) was hydrothermally synthesized and characterized by IR, elemental analysis, UV, TGA, SEM, and single crystal X-ray diffraction analysis. X-ray crystallographic study showed that complex 1 has a two-dimensional double layered hybrid structure containing interconnected 4- and 12-membered rings and shows an unusual (5,5)-con-nected (4~7 · 6~3) (4~8 · 6~2) topology.

机译：水热合成了一种新的膦酸铅（II），Pb [（PO3）2C（OH）CH3]·H2O（1），并通过IR，元素分析，UV，TGA，SEM和单晶X射线衍射分析对其进行了表征。 X射线晶体学研究表明，配合物1具有包含相互连接的4和12元环的二维双层杂化结构，并且显示出不寻常的（5,5）连接（4〜7·6〜3）（ 4〜8·6〜2）拓扑。

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《Inorganic Chemistry Communications》 |2008年第6期|共4页
作者
Shu-Fang Zhang; Zhi Liu; Xiao-Gang Yang;
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正文语种 eng
中图分类无机化学;
关键词
Lead phosphonate; Crystal structure; Layered structure; Topology;

机译：膦酸铅;晶体结构;层状结构;拓扑;

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1. Unprecedented 5,5-connected (4~7 · 6~3) (4~8 · 6~2) structural topology: A lead biphosphonate with double layered structure [J] . Shu-Fang Zhang, Zhi Liu, Xiao-Gang Yang Inorganic Chemistry Communications . 2008,第6期

机译：前所未有的5,5连接（4〜7·6〜3）（4〜8·6〜2）结构拓扑：双层结构的双膦酸铅
2. A Potassium-Lithium Double Salt of Decavanadate Showing Unprecedented(6, 8)-Connected Topology [J] . Lü Yaokang, Feng Yunlong 中国化学（英文版） . 2010,第012期
3. Unprecedented 7-connected 3~6 centre dot 4~13 centre dot 6~2 structural topology:Praseodymium-based coordination polymers built from mixed carboxylate ligands [J] . Peng Ren, Wei Shi, Peng Cheng Inorganic Chemistry Communications . 2008,第1期

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Unprecedented 5,5-connected (4~7 · 6~3) (4~8 · 6~2) structural topology: A lead biphosphonate with double layered structure

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