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首页> 外文期刊>Inorganic Chemistry Communications >A three-dimensional organic-inorganic 3d-4f hybrid polymer constructed with organic pyridinedicarboxylic acid and inorganic lanthanide sulfate skeletons
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A three-dimensional organic-inorganic 3d-4f hybrid polymer constructed with organic pyridinedicarboxylic acid and inorganic lanthanide sulfate skeletons

机译:有机吡啶二羧酸和无机硫酸镧骨架构建的三维有机-无机3d-4f杂化聚合物

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摘要

One 3d-4f heterometallic polymer, namely, {[Eu2Cu(PDC)2(SO4)2(H2O)6]·2H2O}_n (H2PDC = pyridine-3,5-dicarboxylic acid), has been successfully synthesized under hydrothermal conditions and structurally characterized. Single-crystal X-ray diffraction analysis reveals that the polymer features an unusual three-dimensional network structure in which infinite lanthanide-carboxylate chains are linked by [Cu(SO4)2]~(2-) metalloligands to form a mixed-metal coordination network. Furthermore, luminescent property of the hybrid material has also been investigated at room temperature.
机译:一种3d-4f杂金属聚合物,即{[Eu2Cu(PDC)2(SO4)2(H2O)6]·2H2O} _n(H2PDC =吡啶-3,5-二羧酸)已成功合成,并且结构特征。 X射线单晶衍射分析表明该聚合物具有不寻常的三维网络结构,其中无限量镧系元素羧酸盐链通过[Cu(SO4)2]〜(2-)金属配体连接形成混合金属配位网络。此外,还已经在室温下研究了杂化材料的发光性质。

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