Synthesis and reactivity of acetylacetone with amine ligands in fac-Re(OH2)3(CO)_3~+ complexes

Paul D. Benny; Tanushree Ganguly; Lyndel Raiford

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Synthesis and reactivity of acetylacetone with amine ligands in fac-Re(OH2)3(CO)_3~+ complexes

机译：fac-Re（OH2）3（CO）_3〜+配合物中乙酰丙酮与胺配体的合成及反应活性

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The fac-Re(OH2)3(CO)_3~+ moiety was investigated with a known bidentate ligand, acetylactone (acac) and amine based ligands in a 2 +1 and tridentate approach. In the 2 +1 approach, the fac-Re(CO)3(acac)(OH2) was reacted with ethylamine to yield the monomer version fac-Re(CO)3(acac)(NH2Et), 1. Based on the Schiff base condensation of a ketone and a primary amine, a tridentate ligand approach for fac-Re(OH2)3(CO)_3~+ utilizing the reactivity of acac and diamine ligands (1,2 ethylene, 1,3 propylene, 1,4 butylene) was explored in a didactic manner: 1) an in situ ligand synthesis approach reacting fac-Re(CO)3(acac)(OH2) with the diamine (2 + 2 = 3) or 2) direct complexation of fac-Re(OH2)3(CO)_3~+ with the prepared ligand. The results observed with rhenium complexes were characterized by standard chemical analysis and X-ray analysis.

机译：用已知的双齿配体，乙酰基内酯（acac）和胺基配体以2 +1和三齿方式研究了fac-Re（OH2）3（CO）_3〜+部分。在2 +1方法中，使fac-Re（CO）3（acac）（OH2）与乙胺反应，生成单体版本fac-Re（CO）3（acac）（NH2Et），1。酮和伯胺的碱缩合，利用acac和二胺配体（1,2，乙烯，1,3，丙烯，1,4的反应性）制备fac-Re（OH2）3（CO）_3〜+的三齿配体方法丁二烯）的研究方法是：1）通过原位配体合成方法使fac-Re（CO）3（acac）（OH2）与二胺（2 + 2 = 3）或2）fac-Re直接络合（OH2）3（CO）_3〜+与制备的配体。通过标准化学分析和X射线分析对characterized配合物观察到的结果进行表征。

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《Inorganic Chemistry Communications》 |2011年第2期|共4页
作者
Paul D. Benny; Tanushree Ganguly; Lyndel Raiford;
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正文语种 eng
中图分类无机化学;
关键词
Rhenium acac; Complexes; Carbonyl;

机译：hen accomplexes;Carbonyl;

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1. Synthesis and reactivity of acetylacetone with amine ligands in fac-Re(OH2)3(CO)_3~+ complexes [J] . Paul D. Benny, Tanushree Ganguly, Lyndel Raiford Inorganic Chemistry Communications . 2011,第2期

机译：fac-Re（OH2）3（CO）_3〜+配合物中乙酰丙酮与胺配体的合成及反应活性
2. Several Novel N-Donor Tridentate Ligands Formed in Chemical Studies of New fac-Re(CO)(3) Complexes Relevant to fac-Tc-99m(CO)(3) Radiopharmaceuticals: Attack of a Terminal Amine on Coordinated Acetonitrile [J] . Perera T, Marzilli PA, Fronczek FR, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2010,第5期

机译：在与fac-Tc-99m（CO）（3）放射性药物有关的新型fac-Re（CO）（3）配合物的化学研究中形成的几种新型N-供体三齿配体：末端胺对乙腈的攻击
3. Using sterics to promote reactivity in fac-Re(CO)_3 complexes of some 'non-innocent' NNN-pincer ligands [J] . Wanniarachchi S., Liddle B.J., Toussaint J., Dalton transactions: An international journal of inorganic chemistry . 2011,第35期

机译：使用空间来促进某些“非无害” NNN-钳位配体的fac-Re（CO）_3复合物中的反应性
4. Synthesis of Metal Complexes with Tris(oxazolinylmethyl)amine Ligand and Their Catalytic Activity for Alkane Oxidation [C] . Jun Nakazawa, Junpei Endo, Naoki Jyozawa 日本化学会春季年会講演予稿集 . 2018

机译：三（恶唑啉基甲基）胺配体合成金属配合物及其烷烃氧化催化活性
5. Synthesis, characterization, and reactivity of iron(II) and cobalt(II) complexes containing diphosphine ligands that feature a pendant amine base. [D] . Jacobsen, George M. 2007

机译：含有特征为胺侧基的二膦配体的铁（II）和钴（II）配合物的合成，表征和反应性。
6. Several Novel N-Donor Tridentate Ligands Formed in Chemical Studies of New fac-Re(CO)3 Complexes Relevant to fac-99mTc(CO)3 Radiopharmaceuticals. Attack of a Terminal Amine on Coordinated Acetonitrile [O] . Theshini Perera, Patricia A. Marzilli, Frank R. Fronczek, -1

机译：几种新型N-供三齿配体在新面式的Re（CO）3种配合物的相关化学研究形成以面式99mTc（CO）3个放射性药物。终端胺对协调乙腈攻击
7. 2,6-Bis(diphenylphosphinosulfide)pyridine (L) as a facial terdentate ligand: synthesis and characterisation of the tricarbonylrhenium(I) complexes fac-Re(CO)₃L⁺ Re₂(CO)₆(µ-X)₃⁻ (X = Cl, Br or I) and fac-Re(CO)₃L⁺SbF₆⁻. [O] . Heard Peter J, Aliev A E 100

机译：2,6-双（二苯基膦硫醚）吡啶（L）作为面部三齿配体：三羰基铼（I）配合物的合成和表征 - Re（CO）3 L⁺Re 2（CO）₆（μ-X）3 - （X = Cl，Br或I）和fac- Re（CO）3 L⁺sbF₆ - 。

Synthesis and reactivity of acetylacetone with amine ligands in fac-Re(OH2)3(CO)_3~+ complexes

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