Two novel three-dimensional coordination polymer with [Ag(CN)_2]~- as bridging ligands: synthesis and structural characterization of {KMn[Ag(CN)_2]_3 (H_2O)}_n and {Mn[Mg(CN)_2]_2 (bpy)_2}_n (bpy=4,4'-bipyridine)

Wen Dong; Qing-Lun Wang; Shu-Feng Si; Dai-Zheng Liao; Zong-Hui Jiang; Shi-Ping Yan; Peng Cheng

首页> 外文期刊>Inorganic Chemistry Communications >Two novel three-dimensional coordination polymer with [Ag(CN)_2]~- as bridging ligands: synthesis and structural characterization of {KMn[Ag(CN)_2]_3 (H_2O)}_n and {Mn[Mg(CN)_2]_2 (bpy)_2}_n (bpy=4,4'-bipyridine)

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Two novel three-dimensional coordination polymer with [Ag(CN)_2]~- as bridging ligands: synthesis and structural characterization of {KMn[Ag(CN)_2]_3 (H_2O)}_n and {Mn[Mg(CN)_2]_2 (bpy)_2}_n (bpy=4,4'-bipyridine)

机译：[Ag（CN）_2]〜-作为桥联配体的两种新型三维配位聚合物：{KMn [Ag（CN）_2] _3（H_2O）} _ n和{Mn [Mg（CN）_2]的合成与结构表征] _2（bpy）_2} _n（bpy = 4,4'-联吡啶）

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Two novel three-dimensional coordination polymers {KMn[Ag(CN)_2]_3(H_2O)}_n 1 and {Mn[Ag(CN)_2(bpy)]_2}_n 2 have been prepared and structurally as well as magnetically characterized. In both compounds, the three-dimensional networks are constructed entirely by coordinative linkages with all the CN~- anions of [Ag(CN)_2]~-, bpy and water ligands involved in bridging and the novel 3-D structure of 1 is unprecedented.

机译：制备了两种新型的三维配位聚合物{KMn [Ag（CN）_2] _3（H_2O）} _ n 1和{Mn [Ag（CN）_2（bpy）] _ 2} _n 2，并进行了结构和磁学表征。在这两种化合物中，三维网络都是通过与[Ag（CN）_2]〜-，bpy和水配位体中所涉及的所有CN〜-阴离子的架桥连动而构筑的，新型的1D 3-D结构为前所未有。

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来源
《Inorganic Chemistry Communications》 |2003年第7期|共4页
作者
Wen Dong; Qing-Lun Wang; Shu-Feng Si; Dai-Zheng Liao; Zong-Hui Jiang; Shi-Ping Yan; Peng Cheng;
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正文语种 eng
中图分类无机化学;
关键词
dicyanoargentate anion Ag(CN)_2~-; Mn(II) complex; crystal structure;

机译：双氰基阴离子[Ag（CN）_2]〜-;Mn（II）配合物;晶体结构;

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1. Two novel three-dimensional coordination polymer with [Ag(CN)_2]~- as bridging ligands: synthesis and structural characterization of {KMn[Ag(CN)_2]_3 (H_2O)}_n and {Mn[Mg(CN)_2]_2 (bpy)_2}_n (bpy=4,4'-bipyridine) [J] . Wen Dong, Qing-Lun Wang, Shu-Feng Si, Inorganic Chemistry Communications . 2003,第7期

机译：[Ag（CN）_2]〜-作为桥联配体的两种新型三维配位聚合物：{KMn [Ag（CN）_2] _3（H_2O）} _ n和{Mn [Mg（CN）_2]的合成与结构表征] _2（bpy）_2} _n（bpy = 4,4'-联吡啶）
2. Direct Synthesis of the Novel 2-D Mixed-ligands Lead (II) Complex,Crystal Structure of [Pb(4,4'-bpy)(NO_3)(SCN)]_n(4,4'-bpy=4,4'-bipyridine):(A New Polymeric Compound with Three Bridged Ligand and Inactive Lone Pair) [J] . A.Morsali, A.R.Mahjoub Chemistry Letters . 2004,第1期

机译：直接合成新型二维混合配体铅（II）配合物，[Pb（4,4'-bpy）（NO_3）（SCN）] _ n（4,4'-bpy = 4,4'的晶体结构-联吡啶）：(具有三个桥联配体和非活性孤对的新型高分子化合物）
3. New coordination polymer based on a triply bridged dicarboxylate ligand: Synthesis, structure, and magnetic properties of the adipato complex [Cu-4(bpy)(4)(adip)(3)](tcnoet)(2) center dot 2H(2)O {bpy=C10H8N2; adip(2-) = [O2C(CH2)(4)CO2](2-); tcnoet(- [J] . Setifi F, Benmansour S, Triki S, Inorganica Chimica Acta . 2007,第13期

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4. Synthesis and Crystal Structure of a Novel Coordination Polymer Cd(en)(NO3)2(4,4'-bpy)nContaining Three Kinds of Ligands [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

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Two novel three-dimensional coordination polymer with [Ag(CN)_2]~- as bridging ligands: synthesis and structural characterization of {KMn[Ag(CN)_2]_3 (H_2O)}_n and {Mn[Mg(CN)_2]_2 (bpy)_2}_n (bpy=4,4'-bipyridine)

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