Novel platinum complexes having chirality and free tertiary amine groups for multiple interactions with DNA

Mi Sook Seo; Youn Soo Sohn; Wonwoo Nam

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Novel platinum complexes having chirality and free tertiary amine groups for multiple interactions with DNA

机译：具有手性和游离叔胺基团的新型铂配合物，可与DNA进行多次相互作用

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摘要

Chiral ethylenediamine ligands with free tertiary amine groups and their platinum complexes are synthesized.The platinum complexes have both chirality and additional DNA interacting groups.The hydrogen bonding interactions between chlorides and two tertiary amine groups in the crystal structure lead to the dimerization of two platinum complexes having pocket-like cavity with chiral shapes.

机译：合成具有游离叔胺基的手性乙二胺配体及其铂配合物，铂配合物既具有手性又具有额外的DNA相互作用基团，晶体结构中氯化物与两个叔胺基之间的氢键相互作用导致两个铂配合物的二聚化具有手性形状的口袋状空腔。

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来源
《Inorganic Chemistry Communications》 |2004年第11期|共3页
作者
Mi Sook Seo; Youn Soo Sohn; Wonwoo Nam;
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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Chiral amine; Platinum; Anticancer; Multiple DNA interaction;

机译：手性胺;铂;抗癌;多种DNA相互作用;

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专利

1. Novel platinum complexes having chirality and free tertiary amine groups for multiple interactions with DNA [J] . Mi Sook Seo, Youn Soo Sohn, Wonwoo Nam Inorganic Chemistry Communications . 2004,第11期

机译：具有手性和游离叔胺基团的新型铂配合物，可与DNA进行多次相互作用
2. DNA and glutathione interactions in cell-free media of asymmetric platinum(II) complexes cis- and trans-[PtCl2(isopropylamine)(1-methylimidazole)]: relations to their different antitumor effects [J] . Suchankova T, Vojtiskova M, Reedijk J, Journal of biological inorganic chemistry: JBIC: a publication of the Society of Biological Inorganic Chemistry . 2009,第1期

机译：不对称铂（II）配合物顺式和反式[PtCl2（异丙胺）（1-甲基咪唑）]的无细胞培养基中的DNA和谷胱甘肽相互作用：与它们不同的抗肿瘤作用相关
3. DNA and glutathione interactions in cell-free media of asymmetric platinum(II) complexes cis- and trans-[PtCl2(isopropylamine)(1-methylimidazole)]: relations to their different antitumor effects [J] . Tereza Suchánková, Marie Vojtí?ková, Jan Reedijk, JBIC Journal of Biological Inorganic Chemistry . 2009,第1期

机译：不对称铂（II）配合物顺式和反式[PtCl2 （异丙胺）（1-甲基咪唑）]的无细胞培养基中的DNA和谷胱甘肽相互作用：与它们不同的抗肿瘤作用的关系
4. FTIR Study of the Secondary Structure of DNA in Complexes with Platinum Coordination Compounds [C] . E Tymchenko, V Glova, A Soldatova, International Conference PhysicA.SPb . 2020

机译：铂配位化合物复合物中DNA二次结构的FTIR研究
5. THE RESTRICTION ENDONUCLEASE ECO RI: ITS INTRINSIC METAL CENTER AND SPECIFIC INTERACTIONS WITH A DNA RECOGNITION SITE (PROTEIN-NUCLEIC ACID, ZINC METALLOENZYMES, INTERACTIONS CHIRAL METAL COMPLEXES, DNA-BINDING PROTEINS). [D] . PARANAWITHANA, SHANTHI R. 1986

机译：限制性内切酶Eco RI：其内在金属中心以及与DNA识别位点的特定相互作用（蛋白-核酸，锌金属酶，相互作用的手性金属络合物，DNA结合蛋白）。
6. Platinum(II) Terpyridine Anticancer Complexes Possessing Multiple Mode of DNA Interaction and EGFR Inhibiting Activity [O] . Chaoyang Li, Fengmin Xu, Yao Zhao, 2020

机译：铂（II）联吡啶抗癌复合物具有DNA相互作用和EGFR抑制活性的多种模式。
7. Neutral and ionic platinum compounds containing a cyclometallated chiral primary amine: synthesis, antitumor activity, DNA interaction and topoisomerase I–cathepsin B inhibition [O] . Joan Albert, Ramon Bosque, Margarita Crespo, 2015

机译：含有环管替代的手性伯胺的中性和离子铂化合物：合成，抗肿瘤活性，DNA相互作用和拓扑异构酶I-组织蛋白酶B抑制
8. Tertiary Phosphine Complexes of Platinum(Ii) and Palladium(Ii) [R] . Keiter, R. L. 1967

机译：铂（Ii）和钯（Ii）的叔膦配合物

Novel platinum complexes having chirality and free tertiary amine groups for multiple interactions with DNA

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