Regioselective metal-directed self-assembly of a prototype double helical hairpin dinuclear complex

Edwin C.Constable; Inge rAnnette Hougen; Catherine E.Housecroft; Markus Neuburger

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Regioselective metal-directed self-assembly of a prototype double helical hairpin dinuclear complex

机译：双螺旋发夹双核原型的区域选择性金属定向自组装。

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A new type of covalently linked bis(oligopyridine)ligand,4,has been prepared with a spacer group long enough to allow the formation of double helical M_2L complexes;the solid-state structure of[Cu_2(4)][PF_6]_3 shows regioselective formation of the"head-to-tail"hairpin complex.

机译：制备了一种新型的共价连接的双（低聚吡啶）配体4，其间隔基足够长以允许形成双螺旋M_2L配合物; [Cu_2（4）] [PF_6] _3的固态结构显示“头对尾”发夹复合物的区域选择性形成。

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来源
《Inorganic Chemistry Communications》 |2004年第10期|共4页
作者
Edwin C.Constable; Inge rAnnette Hougen; Catherine E.Housecroft; Markus Neuburger;
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正文语种 eng
中图分类无机化学;
关键词
Copper(I); Copper(II); Hairpin complex; Helicate; Oligopyridine ligand;

机译：铜（I）;铜（II）;发夹配合物;螺旋状;寡吡啶配体;

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专利

1. Regioselective metal-directed self-assembly of a prototype double helical hairpin dinuclear complex [J] . Edwin C.Constable, Inge rAnnette Hougen, Catherine E.Housecroft, Inorganic Chemistry Communications . 2004,第10期

机译：双螺旋发夹双核原型的区域选择性金属定向自组装。
2. Complexes of the potentially hexadentate ligand bis{3-[6-(2,2 '-bipyridyl)]pyrazol-1-yl}hydroborate with representative s-, p-, d- and f-block metal ions: factors promoting formation of mononuclear or double-helical dinuclear complexes [J] . Fleming JS., Couchman SM., Jeffery JC., Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1998,第4期

机译：潜在的六齿配体双{3- [6-（2,2'-联吡啶基）]吡唑-1-基}氢硼酸盐与代表性的s，p，d和f嵌段金属离子的配合物：促进形成单核或双螺旋双核复合物
3. Effects of metal co-ordination geometry on self-assembly: a dinuclear double helicate complex and a tetranuclear cage complex of a new bis-bidentate bridging ligand [J] . Paul RL., Jeffery JC., McCleverty JA., Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2000,第6期

机译：金属配位几何形状对自组装的影响：双双齿桥联配体的双核双螺旋配合物和四核笼状配合物
4. Dinuclear Copper(II) Complexes for Regioselective Glycoside Oxidation [C] . Susanne Striegler Conference on the Catalysis of Organic Reactions . 2009

机译：用于区域选择性糖苷氧化的二核铜（II）复合物
5. New chemistry with gold-nitrogen complexes: Synthesis and characterization of tetra-, tri-, and dinuclear gold(I) amidinate complexes, oxidative-addition to the dinuclear gold(I) amidinate. [D] . Abdou, Hanan Elsayed. 2006

机译：金-氮配合物的新化学方法：四核，三核和双核a金（I）配合物的合成与表征，,化双核金（I）的氧化加成反应。
6. One-Pot Self-Assembly of Dinuclear Tetranuclear and H-Bonding-Directed Polynuclear Cobalt(II) Cobalt(III) and Mixed-Valence Co(II)/Co(III) Complexes of Schiff Base Ligands with Incomplete Double Cubane Core [O] . Santokh S. Tandon, Neil Patel, Scott D. Bunge, 2020

机译：二核四核和H键合的多核钴（II）钴（III）和混合价CO（II）/ CO（III）复合物的单核四核和H键合的多核钴（II）具有不完全的双副Cubane核
7. One-Pot Self-Assembly of Dinuclear, Tetranuclear, and H-Bonding-Directed Polynuclear Cobalt(II), Cobalt(III), and Mixed-Valence Co(II)/Co(III) Complexes of Schiff Base Ligands with Incomplete Double Cubane Core [O] . Santokh S. Tandon, Neil Patel, Scott D. Bunge, 2020

机译：二核，四核和H键合的多核钴（II），钴（III）和混合价CO（II）/ CO（III）复合物的单核，四核和H键合的多核钴（II），具有不完全的双副Cubane核

Regioselective metal-directed self-assembly of a prototype double helical hairpin dinuclear complex

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