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首页> 外文期刊>Inorganic Chemistry Communications >Two-dimensional organic-inorganic hybrid materials based on β-octamolybdate units linked by [{Cu(imi)(phen)}2Cl]~(3+) and K~+ bridges
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Two-dimensional organic-inorganic hybrid materials based on β-octamolybdate units linked by [{Cu(imi)(phen)}2Cl]~(3+) and K~+ bridges

机译:基于[{Cu(imi)(phen)} 2Cl]〜(3+)和K〜+桥连接的β-八钼酸盐单元的二维有机-无机杂化材料

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摘要

A new organic-inorganic hybrid material, formulated as K[{Cu(imi)(phen)}2Cl][Mo8O_(26)] (1) (imi = imidazole, phen = 1,10-phenanthroline), has been synthesized under hydrothermal conditions and structurally characterized by elemental analysis, IR spectra, thermal analysis and single-crystal X-ray diffraction. Compound 1 consisted of β-[Mo8O_(26)]~(4-) cluster, dinuclear copper complex [Cu(imi)(phen)2Cl]~(3+) and K~+ ion, in which the β-octaolybdate building block is linked by the coordination bridge [Cu(imi)(phen)2Cl]~(3+) and the inorganic bridge K~+ into a 2D organic-inorganic framework through M-O-M' bonds (M = Mo, M' = Cu, K). The electrochemical behavior of compound 1 has been studied in detail based on a solid bulk-modified carbon paste electrode of compound 1 (1-CPE).
机译:在以下条件下合成了一种新的有机-无机杂化材料:K [{Cu(imi)(phen)} 2Cl] [Mo8O_(26)](1)(imi =咪唑,phen = 1,10-菲咯啉)水热条件,并通过元素分析,红外光谱,热分析和单晶X射线衍射进行结构表征。化合物1由β-[Mo8O_(26)]〜(4-)团簇,双核铜络合物[Cu(imi)(phen)2Cl]〜(3+)和K〜+离子组成,其中β-八溴酸盐结构嵌段通过配位桥[Cu(imi)(phen)2Cl]〜(3+)和无机桥K〜+通过MOM'键(M = Mo,M'= Cu, K)。已基于化合物1(1-CPE)的固体本体改性碳糊电极对化合物1的电化学行为进行了详细研究。

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