Solvothermal syntheses, characterizations and properties of two new Ni~(II)-PMIDA phosphonates

Kui-Rong Ma; Jia-Ning Xu; De-Kuan Ning

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Solvothermal syntheses, characterizations and properties of two new Ni~(II)-PMIDA phosphonates

机译：两种新型Ni〜（II）-PMIDA膦酸酯的溶剂热合成，表征和性质

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摘要

Two new nickel(II) phosphonates (H4PMIDA = N-(phosphonomethyl)iminodiacetic acid, H4L), one-dimensional zigzag chain (NH4)2[Ni(PMIDA)(H2O)] (1) and tetramer (H3O)8[Ni4O2(HPMIDA)4(H2O)2] (2), have been solvothermally synthesized and characterized by elemental analyses, IR, TGA and X-ray single-crystal diffraction, and their magnetic and fluorescent properties are also reported. Compound 1 is the first chain phosphonate linked by carboxyl group in anti-anti mode based on Ni(II) and H4PMIDA ligand, and compound 2 with tetranuclear units is the first example of showing the spin-canting antiferromagnetic coupling between Ni(II) centers.

机译：两个新的膦酸镍（II）（H4PMIDA = N-（膦酰基甲基）亚氨基二乙酸，H4L），一维之字形链（NH4）2 [Ni（PMIDA）（H2O）]（1）和四聚体（H3O）8 [Ni4O2 （HPMIDA）4（H2O）2]（2）已被溶剂热合成并通过元素分析，IR，TGA和X射线单晶衍射表征，并且还报道了它们的磁性和荧光性质。化合物1是基于Ni（II）和H4PMIDA配体的反链方式通过羧基连接的第一链膦酸酯，具有四核单元的化合物2是显示Ni（II）中心之间自旋消除反铁磁偶联的第一个例子。

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《Inorganic Chemistry Communications》 |2009年第2期|共3页
作者
Kui-Rong Ma; Jia-Ning Xu; De-Kuan Ning;
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正文语种 eng
中图分类无机化学;
关键词
Ni(II) phosphonate; Solvothermal; Magnetism; Fluorescence;

机译：膦酸镍（II）;溶剂热;磁性;荧光;

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1. Solvothermal syntheses, characterizations and properties of two new Ni~(II)-PMIDA phosphonates [J] . Kui-Rong Ma, Jia-Ning Xu, De-Kuan Ning Inorganic Chemistry Communications . 2009,第2期

机译：两种新型Ni〜（II）-PMIDA膦酸酯的溶剂热合成，表征和性质
2. Solvothermal synthesis and characterization of a new ZnII-PMIDA phosphonate [J] . Ma Kui-Ronga* Zhu Yu-Lana amp, Yin Qi-Fana Journal of Co-ordination Chemistry . 2009,第20期

机译：Zn II -PMIDA膦酸酯的溶剂热合成及表征
3. Solvothermal syntheses, characterizations and properties of three transition metal (Ni(II), Co(II)) imino-carboxylate-diphosphonates [J] . Kuirong Ma, Jianing Xu, Lirong Zhang New Journal of Chemistry . 2009,第4期

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4. Synthesis and characterization of a new weak ferromagnet: Fe(II) ethylene-Bis-(phosphonates) [C] . C. Bellitto, F. Federici, M.R. Mahmoud, Symposium on Solid-State chemistry of inorganic materials . 1999

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Solvothermal syntheses, characterizations and properties of two new Ni~(II)-PMIDA phosphonates

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