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首页> 外文期刊>Inorganic Chemistry Communications >A new bitrack sinusoid-like chain templated by Wells-Dawson type polyoxometalate
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A new bitrack sinusoid-like chain templated by Wells-Dawson type polyoxometalate

机译:Wells-Dawson型多金属氧酸盐为模板的新型双轨正弦样链

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摘要

A new Wells-Dawson type polyoxometalate (POM)-templated compound, [Cu4(μ2-O)2(4,4'-bpo)4(INA)2 (H2O)4][(P2W_(18)O_(62))]·H2O (1) (4,4'-bpo = 2,5-bis(4-pyridyl)-1,3,4-oxadiazole; INA = pyridine-4-carboxylic acid), has been hydrothermally synthesized. Compound 1 contains a novel bitrack sinusoid-like chain constructed from alternating dicopper units and non-linear rigid 4,4'-bpo linkers. Induced by POM templates, the adjacent chains formed elliptical spaces to accommodate the Wells-Dawson type anions.
机译:新型Wells-Dawson型多金属氧酸盐(POM)模板化合物[Cu4(μ2-O)2(4,4'-bpo)4(INA)2(H2O)4] [(P2W_(18)O_(62) )]·H2O(1)(4,4'-bpo = 2,5-双(4-吡啶基)-1,3,4-恶二唑; INA =吡啶-4-羧酸),已经水热合成。化合物1包含由交替的双铜单元和非线性刚性4,4'-bpo接头构成的新型双轨正弦样链。由POM模板诱导,相邻的链形成椭圆形空间以容纳Wells-Dawson型阴离子。

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