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Assembly of a 3D chiral Cu(I) metal-organic framework based on 4,5-dicyanoimidazole: CD spectrum, luminescence and selective gas adsorption

机译:基于4,5-二氰基咪唑的3D手性Cu(I)金属有机骨架的组装:CD光谱,发光和选择性气体吸附

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摘要

One chiral Cu(I) metal-organic framework {[Cu(DCI)]center dot 0.1Cyc center dot 0.45Nbenz}(n) (1) (HDCI = 4,5-dicyanoimidazole, Cyc = cyclohexanol, Nbenz = nitrobenzene), was obtained under solvothermal condition. Complex 1 presents a 3D chiral porous framework with 38.2% porosity. The 3D metal-organic framework can be regarded as a PtS net with the vertex symbol of {4(2).8(4)}. The gas adsorption/desorption experiments of complex 1 have been measured at 77 K. Moreover, the CD spectrum and photoluminescent behavior of complex 1 have been studied. (C) 2016 Elsevier B.V. All rights reserved.
机译:一个手性Cu(I)金属有机骨架{[Cu(DCI)]中心点0.1Cyc中心点0.45Nbenz}(n)(1)(HDCI = 4,5-二氰基咪唑,Cyc =环己醇,Nbenz =硝基苯),在溶剂热条件下获得。配合物1呈现具有38.2%孔隙率的3D手性多孔骨架。 3D金属有机框架可以视为顶点符号为{4(2).8(4)}的PtS网络。在77 K下测量了配合物1的气体吸附/解吸实验。此外,还研究了配合物1的CD光谱和光致发光行为。 (C)2016 Elsevier B.V.保留所有权利。

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