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The first bromonicotinato-coordinated metal-organic polymer featuring covalent 2-D layer alternately sandwiched by 1-D intra-hydrogen bonding networks

机译:第一种具有共价2维层,由一维氢内键合网络交替夹在中间的溴代维生素A配位的金属有机聚合物

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摘要

A unique 2-D coordination network sandwiched by alternating 1-D intra-hydrogen bonding networks has been synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction technique and thermal analysis,[(H_2O)Mn(BN)_2] (BN=bromonicotinato) crystallized in monoclinic crystal system,space group P2_1/c with unit cell dimensions a=10.385(1),b=10.151(1) and c=7.156(1),A,beta=98.119 (1) deg,Z=2.
机译:在水热条件下合成了由交替的1-D氢内键合网络夹持的独特的2-D配位网络,并通过单晶X射线衍射技术和热分析[[H_2O] Mn(BN)_2](BN = bromonicotinato)在单斜晶体系统中结晶,空间群P2_1 / c的晶胞尺寸a = 10.385(1),b = 10.151(1)和c = 7.156(1),A,β= 98.119(1)deg,Z = 2。

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