A chair-piperazine bridged N,N-dimethylformamide coordinated dicopper(II/II) complex obtained via solution transformation of heterocyclic imidazolidine spacer of a new ligand

Manindranath Bera; Debashis Ray; Joan Ribas

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A chair-piperazine bridged N,N-dimethylformamide coordinated dicopper(II/II) complex obtained via solution transformation of heterocyclic imidazolidine spacer of a new ligand

机译：椅子-哌嗪桥联的N，N-二甲基甲酰胺配位的双铜（II / II）配合物，通过新配体的杂环咪唑烷间隔基的溶液转化获得

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摘要

First N,N-dimethylformamide coordinated chair-piperazine bridged dicopper(H/II) complex [Cu_2~(II)(mu-L)(DMF)_2](ClO)_4)_2 was obtained following a solution transformation of the heterocyclic imidazolidine spacer of the new mu-bis(tridentate) ligand (H_2L').

机译：杂环咪唑烷经溶液转化后，首先得到N，N-二甲基甲酰胺配位的椅子-哌嗪桥联的双铜（H / II）络合物[Cu_2〜（II）（mu-L）（DMF）_2]（ClO）_4）_2。 mu-bis（三齿）配体（H_2L'）的间隔基。

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《Inorganic Chemistry Communications》 |2004年第11期|共4页
作者
Manindranath Bera; Debashis Ray; Joan Ribas;
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正文语种 eng
中图分类无机化学;
关键词
Bis(tridentate); Imidazolidine ring; Schiff base; Dicopper complex; Crystal structure; Magnetic properties;

机译：双（三齿）;咪唑烷环;席夫碱;狄科珀配合物;晶体结构;磁性;

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1. A chair-piperazine bridged N,N-dimethylformamide coordinated dicopper(II/II) complex obtained via solution transformation of heterocyclic imidazolidine spacer of a new ligand [J] . Manindranath Bera, Debashis Ray, Joan Ribas Inorganic Chemistry Communications . 2004,第11期

机译：椅子-哌嗪桥联的N，N-二甲基甲酰胺配位的双铜（II / II）配合物，通过新配体的杂环咪唑烷间隔基的溶液转化获得
2. Imidazolidine ring as a reduced heterocyclic spacer in a new all-N-donor e???-bis(bidentate) Schiff base ligand: Synthesis, characterization and electron transfer properties of imidazolidine-bridged dicopper complexes [J] . Debashis Ray1, Manindranath Bera, Prasant Kumar Nanda, Journal of Chemical Sciences . 2004,第3期

机译：咪唑烷环作为新型全N-供体e ???-双（双齿）席夫碱配体中的还原杂环间隔基：咪唑烷桥联的双铜配合物的合成，表征和电子转移性质
3. mu-eta~1:eta~1-N,N'-Imidazolidine-Bridged Dicopper(II/III)Complexes of a New Dinucleating mu-Bis(tetradentate)Schiff Base Ligand:Synthesis,Structural Characterization,~1H NMR Spectroscopy,and Magnetic Coupling [J] . Manindranath Bera, Wing Tak Wong, Guillem Aromi, European journal of inorganic chemistry . 2005,第12期

机译：新型成核mu-Bis（四齿）席夫碱配体的mu-eta〜1：eta〜1-N，N'-咪唑烷桥联双铜（II / III）配合物：合成，结构表征，〜1H NMR光谱和磁耦合
4. Synthesis of Phenylpyridine Iridium(III) Complexes with N-Heterocyclic Carbene as Ancillary Ligands [C] . N H A Bain, N M Ali, Y Juahir International Fundamentum Science Symposium . 2019

机译：用N-杂环烷烃作为辅助配体的合成苯吡啶铱（III）配合物
5. Homobinuclear transition metal complexes of hexaazamacrocycles: Reactivity with carbon-dioxide, a uniquely bridged tetracopper(II) oxalate complex, and a monohydroxide bridged dicopper(II) model of hemocyanin and tyrosinase. [D] . Kelly, Gregg Robert Daniel. 1987

机译：六氮杂大环的同核过渡金属配合物：与二氧化碳，唯一桥联的草酸四铜（II）复合物和血色素和酪氨酸酶的单羟基桥联的二铜（II）模型的反应性。
6. Crystal structure of a CuII complex with a bridging ligand: polypentakisμ2-11′-(butane-14-diyl)bis(1H-imidazole)-κ2N3:N3′dicopper(II) tetranitrate tetrahydrate [O] . Fayuan Wu, Mengxiang Shang, Shihua Li, 2014

机译：具有桥联配体的CuII配合物的晶体结构：聚五烷基2-11-（丁烷-14-二烷基）双（1H-咪唑）-κ2ñ3：N3二铜（II）四硝酸四水合物
7. Imidazolidine ring as a reduced heterocyclic spacer in a new all-N-donor μ-bis (bidentate) Schiff base ligand: Synthesis, characterization and electron transfer properties of imidazolidine-bridged dicopper complexes [O] . Manindranath Bera, Prasant Kumar Nanda, Uday Mukhopadhyay, 2004

机译：咪唑烷烃环作为一种新的全-N-供体μ-BIS（二齿）Schiff碱配体：咪唑烷桥桥络合物的合成，表征和电子转移性能

A chair-piperazine bridged N,N-dimethylformamide coordinated dicopper(II/II) complex obtained via solution transformation of heterocyclic imidazolidine spacer of a new ligand

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