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Two novel luminescent zinc supramolecular networks with nicotinate derivatives by hydrothermal process

机译:水热法制备的两个具有烟酸酯衍生物的新型发光锌超分子网络

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摘要

Two novel zinc compounds [Zn(Enic)_2]_n,(1)(Enic=5-ethylnicotinate)and [Zn(H_2O)_6][6-OHnic]_2(2)(6-OHnic=6-hydroxynicoti-nate)have been synthesized under hydrothermal reaction conditions.The structure of the compound 1 is self-assembled from square-grid nets stacked via interdigitation while compound 2 forms a 3D supermolecular network structure via strong O-H…O hydrogen bond.In addition,the luminescent properties of two compounds were investigated in the crystalline state.
机译:两种新型锌化合物[Zn(Enic)_2] _n,(1)(Enic = 5-乙基烟酸酯)和[Zn(H_2O)_6] [6-OHnic] _2(2)(6-OHnic = 6-羟基烟酸酯化合物1的结构是由相互交叉叠置的方格网自组装而成的,而化合物2则是通过强OH ... O氢键形成3D超分子网络结构的。研究了两种化合物的结晶状态。

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