Macropolyhedral borane reaction chemistry:Reductive oligomerisation of ~terBuNC by anti-B_18H_22 to give the boron-coordinated {(~terBuNHCH){~terBuNHC(CN)}CH_2:}carbene residue

Tomas Jelinek; Colin A.Kilner; Simon A.Barrett; Bohumil Stibr; Mark Thornton-Pett

首页> 外文期刊>Inorganic Chemistry Communications >Macropolyhedral borane reaction chemistry:Reductive oligomerisation of ~terBuNC by anti-B_18H_22 to give the boron-coordinated {(~terBuNHCH){~terBuNHC(CN)}CH_2:}carbene residue

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Macropolyhedral borane reaction chemistry:Reductive oligomerisation of ~terBuNC by anti-B_18H_22 to give the boron-coordinated {(~terBuNHCH){~terBuNHC(CN)}CH_2:}carbene residue

机译：大面体硼烷反应化学：〜terBuNC被抗-B_18H_22还原低聚，得到硼配位的{（〜terBuNHCH）{〜terBuNHC（CN）} CH_2：}碳烯残基

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Reaction of ~terBuNC with anti-B_18H_22 in CH_2C1CH_2C1 gives [7-{(~terBuNHCH){~terBuNHC(CN)}CH_2}-anti-B_18H_20] in which a reductive oligomerisation of the ~terBuNC residues has given the complex polynitrogen base {(~terBuNHCH){~terBuNHC(CN)}CH_2:},formally as a zwitterionic carbene attached to the macropolyhedral {B_18H_20} cluster.

机译：〜terBuNC与CH_2C1CH_2C1中的抗B_18H_22反应得到[7-{（〜terBuNHCH）{〜terBuNHC（CN）} CH_2}-抗B_18H_20]，其中〜terBuNC残基的还原性低聚反应给出了复杂的多氮碱基{ （〜terBuNHCH）{〜terBuNHC（CN）} CH_2：}，形式上是两性离子卡宾烯，附着在大面体{B_18H_20}簇上。

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《Inorganic Chemistry Communications》 |2005年第5期|共4页
作者
Tomas Jelinek; Colin A.Kilner; Simon A.Barrett; Bohumil Stibr; Mark Thornton-Pett;
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正文语种 eng
中图分类无机化学;
关键词
Borane cluster; X-ray structure; NMR spectroscopy; Polynitrogen base formation; Macropolyhedral cluster; Isocyanide oligomer; Carbene ligand;

机译：硼烷簇;X射线结构;NMR光谱;多氮碱形成;宏观多面体簇;异氰化物低聚物;碳烯配体;

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外文文献

1. Macropolyhedral borane reaction chemistry:Reductive oligomerisation of ~terBuNC by anti-B_18H_22 to give the boron-coordinated {(~terBuNHCH){~terBuNHC(CN)}CH_2:}carbene residue [J] . Tomas Jelinek, Colin A.Kilner, Simon A.Barrett, Inorganic Chemistry Communications . 2005,第5期

机译：大面体硼烷反应化学：〜terBuNC被抗-B_18H_22还原低聚，得到硼配位的{（〜terBuNHCH）{〜terBuNHC（CN）} CH_2：}碳烯残基
2. Radical Reactions of N-Heterocyclic Carbene Boranes with Organic Nitriles: Cyanation of NHC-Boranes and Reductive Decyanation of Malononitriles [J] . Takuji Kawamoto, Steven J. Geib, Dennis P. Curran Journal of the American Chemical Society . 2015,第26期

机译：N-杂环碳硼烷与有机腈的自由基反应：NHC-硼烷的氰化和丙二腈的还原性脱氰

Macropolyhedral borane reaction chemistry:Reductive oligomerisation of ~terBuNC by anti-B_18H_22 to give the boron-coordinated {(~terBuNHCH){~terBuNHC(CN)}CH_2:}carbene residue

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