Unprecedented strong blue fluorescent cadmium(II)coordination polymer based on neutral and deprotonated 3-hydroxypyridine ligands

Shan Gao; Zhen-Zhong Lu; Li-Hua Huo; Hui Zhao; Jing-Gui Zhao

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Unprecedented strong blue fluorescent cadmium(II)coordination polymer based on neutral and deprotonated 3-hydroxypyridine ligands

机译：基于中性和去质子化的3-羟基吡啶配体的史无前例的强蓝色荧光镉（II）配位聚合物

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摘要

A novel two-dimensional sheet cadmium(II)coordination polymer[Cd(mu-3-PyO-N,O)_2(3-PyOH)_2]_n,containing neutral and deprotonated 3-hydroxypyridine ligands has been synthesized and shown to exhibit strong blue fluorescent emission in the solid state.Polynuclear d~(10)metal[Cu(I),Ag(I),Au(I),Zn(II)or Cd(II)]complexes are of growing interest for the study of new bright blue luminescent materials in the development of light emitting diode(LED)technology[1,2],since these complexes been found to exhibit strong emission under UV irradiation and the emission energies can span over a broad spectral range(400-700 nm)[3-5].

机译：合成了一种新型的二维片状镉（II）配位聚合物[Cd（mu-3-PyO-N，O）_2（3-PyOH）_2] _n，它含有中性和去质子化的3-羟基吡啶配体固态d〜（10）金属[Cu（I），Ag（I），Au（I），Zn（II）或Cd（II）]复合物越来越受到研究的关注发光二极管（LED）技术的发展中，新的亮蓝色发光材料的发展[1,2]，因为发现这些络合物在紫外线辐射下表现出强发射，并且发射能量可以跨越很宽的光谱范围（400-700） nm）[3-5]。

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来源
《Inorganic Chemistry Communications》 |2005年第1期|共3页
作者
Shan Gao; Zhen-Zhong Lu; Li-Hua Huo; Hui Zhao; Jing-Gui Zhao;
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正文语种 eng
中图分类无机化学;
关键词
Cd coordination polymer; Fluorescent property; 3-hydroxypyridine;

机译：镉配位聚合物;荧光性能;3-羟基吡啶;

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1. Unprecedented strong blue fluorescent cadmium(II)coordination polymer based on neutral and deprotonated 3-hydroxypyridine ligands [J] . Shan Gao, Zhen-Zhong Lu, Li-Hua Huo, Inorganic Chemistry Communications . 2005,第1期

机译：基于中性和去质子化的3-羟基吡啶配体的史无前例的强蓝色荧光镉（II）配位聚合物
2. Initial use of 1-hydroxybenzotriazole in the chemistry of group 12 metals: An 1D zinc(II) coordination polymer and a mononuclear cadmium(II) complex containing the deprotonated ligand in a novel monodentate ligation mode [J] . Athanassios D. Katsenis, Nikolia Lalioti, Vlasoula Bekiari Inorganic Chemistry Communications . 2009,第2期

机译：1-羟基苯并三唑在第12组金属的化学中的初步使用：一种一维锌（II）配位聚合物和一种以新的单齿连接模式包含去质子化配体的单核镉（II）配合物
3. A two-dimensional Cd(II) coordination polymer:[Cd(l,4-BDOA)(l,10-phen)] centre dot H_2O with strong blue fluorescent emission constructed by benzene-1,4-dioxydiacetate ligand [J] . Shan Gao, Li-Hua Huo, Ying-Ming Xu, Inorganic Chemistry Communications . 2005,第4期

机译：二维Cd（II）配位聚合物：[Cd（1,4-BDOA）（1,10-phen）]中心点H_2O，由苯-1,4-二氧二乙酸酯配体构成，具有强蓝色荧光发射
4. Coordination/Organometallic Polymers Based on Diphosphine and Diisocyanide Ligands [C] . Pierre D. Harvey Metal- and Metalloid-Containing Macromolecules . 2003

机译：基于二膦和二异氰酸酯配体的配位/有机金属聚合物
5. I. The synthesis and coordination chemistry of novel 1,1,1-tris(aminomethyl)ethane (TAME) derived ligands and their use as size selective fluorescent zinc(II) sensors. II. The synthesis of strongly and weakly binding ligands with nitrogen, oxygen, and sulfur-donor groups to be used as receptors in fluorescent ratiometric indicators for transition metal ions. [D] . Kennedy, Daniel Patrick. 2007

机译：I.新型1,1,1-三（氨基甲基）乙烷（TAME）衍生的配体的合成和配位化学及其作为尺寸选择荧光锌（II）传感器的用途。二。具有氮，氧和硫供体基团的强结合和弱结合配体的合成，将用作过渡金属离子的荧光比率指示剂中的受体。
6. ‘Metal Complexes as Ligands’ for the Synthesis of Coordination Polymers: A MnIII Monomer as a Building Block for the Preparation of an Unprecedented 1-D {MnIIMnIII}n Linear Chain [O] . Konstantinos N. Pantelis, Georgios Karotsis, Christos Lampropoulos, 2020

机译：用于配位聚合物合成的金属配体配体：MnIII单体作为构建空前的1-D {MnIIMnIII} n线性链的基础
7. Exploiting a new europium(III) coordination polymer based on a zwitterionic ligand as a fluorescent probe for uranyl cations [O] . Bin Cai, Yu-Ning Meng, Meng-En Zhu, 2020

机译：利用基于两性离子配体的新型铕（III）配位聚合物作为铀酰阳离子的荧光探针

Unprecedented strong blue fluorescent cadmium(II)coordination polymer based on neutral and deprotonated 3-hydroxypyridine ligands

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