A new three-dimensional Cu(II)coordination polymer with triaminoguanidin building blocks

Aksana Zharkouskaya; Helmar Gorls; Gavin Vaughan; Winfried Plass

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A new three-dimensional Cu(II)coordination polymer with triaminoguanidin building blocks

机译：具有三氨基胍结构单元的新型三维Cu（II）配位聚合物

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摘要

The reaction between the tris(2-hydroxybenzylidene)triaminoguanidin hydrochloride(H_6L)Cl and copper(II)chloride in the presence of triethylamine leads to a three-dimensional coordination polymer with two interpenetrating(10,3)-a networks of opposite chirality.Magnetic studies revealed strong antiferromagnetic coupling between copper ions of the spin frustrated trinuclear building unit.

机译：在三乙胺存在下，三（2-羟基亚苄基）三氨基胍盐酸盐（H_6L）Cl与氯化铜（II）之间的反应生成具有两个相互渗透的（10,3）-a手性相反的网络的三维配位聚合物。磁性研究表明，自旋受阻的三核建筑单元的铜离子之间存在强反铁磁耦合。

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来源
《Inorganic Chemistry Communications》 |2005年第12期|共4页
作者
Aksana Zharkouskaya; Helmar Gorls; Gavin Vaughan; Winfried Plass;
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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Coordination polymer; Copper(II)complex; Crystal structure; Magnetic properties; Self-assembly;

机译：配位聚合物;铜（II）配合物;晶体结构;磁性;自组装;

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专利

1. A new three-dimensional Cu(II)coordination polymer with triaminoguanidin building blocks [J] . Aksana Zharkouskaya, Helmar Gorls, Gavin Vaughan, Inorganic Chemistry Communications . 2005,第12期

机译：具有三氨基胍结构单元的新型三维Cu（II）配位聚合物
2. 1D, 2D and 3D coordination polymers of 1,3-phenylene diisonicotinate with Cu(I)/Cu(II): Cu2I2 building block, anion influence and guest inclusions [J] . Mukherjee Gargi, Biradha Kumar CrystEngComm . 2014,第22期

机译：1,3-亚苯基二异烟酸酯与Cu（I）/ Cu（II）的1D，2D和3D配位聚合物：Cu2I2结构单元，阴离子影响和客体夹杂物
3. A Cu~(II)-Gd~(II)-Cu~(II) heterometallic coordination polymer constructed by gadolinium(III) ion and copper(II) Schiff-base building block: Structure and magnetic property [J] . Yang Zou, Fei Yin, Xiao-Jun Zhou Inorganic Chemistry Communications . 2014,第Null期

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4. Synthesis and Electrochemistry of Pt~(II) 2Cu~(II) 2Zn~(II) Coordination Polymers with D-Penicillaminate [C] . Naoto Kuwamura, Yoshinari Kurioka, Takumi Konno 日本化学会春季年会講演予稿集 . 2018

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5. Octahedral metal clusters as molecular building blocks of coordination polymers: Synthesis, characterization, and study of their host-guest interactions. [D] . Chen, Lei. 2011

机译：八面体金属簇作为配位聚合物的分子构建基块：合成，表征和研究其主客体相互作用。
6. Tetracarbonatodiruthenium Fragments and Lanthanide(III) Ions as Building Blocks to Construct 2D Coordination Polymers [O] . Daniel Gutiérrez-Martín, Miguel Cortijo, Álvaro Martín-Humanes, 2019

机译：四碳二钌钌片段和镧系元素（III）离子作为构建2D配位聚合物的基础
7. Synthesis and Crystal Structure of a One-dimensional Cu(II) Coordination Polymer Bridged by Inorganic CH3SO3- Anions Using Werner-type Cu(II) Complexes as Building Blocks [O] . Noro, Shin-ichiro, Kubo, Kazuya, Nakamura, Takayoshi 2012

机译：以Werner型Cu（II）配合物为构建基的无机CH3SO3-阴离子桥联的一维Cu（II）配位聚合物的合成和晶体结构

A new three-dimensional Cu(II)coordination polymer with triaminoguanidin building blocks

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