[SmNi(pic)_3(H_2O)_5]_N(ClO_4)_(2n)centre dot 3nH_2O,the first Sm-Ni heterometallic complex of picolinic acid ligand showing novel basket weave topology:Synthesis,structure and magnetics

A-Qing Wu; Guang-Hua Guo; Fa-Kun Zheng; Ming-Sheng Wang; Yan Li

首页> 外文期刊>Inorganic Chemistry Communications >[SmNi(pic)_3(H_2O)_5]_N(ClO_4)_(2n)centre dot 3nH_2O,the first Sm-Ni heterometallic complex of picolinic acid ligand showing novel basket weave topology:Synthesis,structure and magnetics

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[SmNi(pic)_3(H_2O)_5]_N(ClO_4)_(2n)centre dot 3nH_2O,the first Sm-Ni heterometallic complex of picolinic acid ligand showing novel basket weave topology:Synthesis,structure and magnetics

机译：[SmNi（pic）_3（H_2O）_5] _N（ClO_4）_（2n）中心点3nH_2O，第一个吡啶甲酸配体的Sm-Ni杂金属配合物，显示出新颖的篮式编织拓扑：合成，结构和磁性

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摘要

The first basket weave framework topology of Sm-Ni heterometallic complex with picolinic acid as bridging ligand showing two different coordination modes of picolinic acid has been characterized;The studies on temperature-dependent magnetization indicate the title complex follows the Curie-Wiess paramagnetic behavior down to 5 K.

机译：Sm-Ni杂金属配合物为桥联配体的第一个篮子编织构架拓扑结构已被表征，显示出两种不同的吡啶甲酸配位模式;对温度依赖性磁化的研究表明标题化合物遵循居里-威斯顺磁行为直至5K。

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来源
《Inorganic Chemistry Communications》 |2005年第12期|共4页
作者
A-Qing Wu; Guang-Hua Guo; Fa-Kun Zheng; Ming-Sheng Wang; Yan Li;
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正文语种 eng
中图分类无机化学;
关键词
Ln-Ni heterometallic complexes; Crystal structures; Magnetic properties; Topology;

机译：Ln-Ni杂金属配合物;晶体结构;磁性;拓扑;

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1. [SmNi(pic)_3(H_2O)_5]_N(ClO_4)_(2n)centre dot 3nH_2O,the first Sm-Ni heterometallic complex of picolinic acid ligand showing novel basket weave topology:Synthesis,structure and magnetics [J] . A-Qing Wu, Guang-Hua Guo, Fa-Kun Zheng, Inorganic Chemistry Communications . 2005,第12期

机译：[SmNi（pic）_3（H_2O）_5] _N（ClO_4）_（2n）中心点3nH_2O，第一个吡啶甲酸配体的Sm-Ni杂金属配合物，显示出新颖的篮式编织拓扑：合成，结构和磁性
2. Synthesis and structures of carboxylate-bridged polynuclear copper (II)-lanthanide (III) complexes (CuLn(C_5H_5N~+CH_2CO_2~-)_5(H_2O)_5)(ClO_4)_5 centre dot 2H_2O (Ln = La or Nd) and (Cu_3Nd_2(C_5H_5N~+CH_2CO_2~-)_(10)(NO_3)_2(H_2O)_8) (ClO_4)_(10) c [J] . Yang-Yi Yang, Yu-Luan Wu, La-Sheng Long, Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1999,第12期

机译：羧酸桥联多核铜（II）-镧系元素（III）（CuLn（C_5H_5N〜+ CH_2CO_2〜-）_ 5（H_2O）_5）（ClO_4）_5中心点2H_2O（Ln = La或Nd）和（ Cu_3Nd_2（C_5H_5N〜+ CH_2CO_2〜-）_（10）（NO_3）_2（H_2O）_8）（ClO_4）_（10）c
3. New mixed-anion zinc(II) complexes, [Zn(phen)_2(CCl_3COO)(H_2O)](NO_3)and [Zn(bpy)_2(CH_3COO)](ClO_4) centre dot H_2O; synthesis, characterization and crystal structures [J] . ZEANAB TALAEI, ALI MORSALI, ALI R. MAHJOUB Journal of Coordination Chemistry . 2006,第6期

机译：新的混合阴离子锌（II）配合物，[Zn（phen）_2（CCl_3COO）（H_2O）]（NO_3）和[Zn（bpy）_2（CH_3COO）]（ClO_4）中心点H_2O;合成，表征和晶体结构
4. Cyanido-Bridged Heterometallic Oligonuclear Complexes and Coordination Polymers Constructed Using Tridentate Schiff-Base Ligands: Synthesis, Crystal Structures, and Magnetic and Luminescence Properties. A New Trimeric Water Cluster [O] . C. Maxim, F. Tuna, A.M. Madalan, 2012

机译：Cyanido-Bridged异金属寡核配合物和配位聚合物使用三齿希夫碱配体构建：合成，晶体结构，磁性和发光性质。一种新的三聚体水簇

[SmNi(pic)_3(H_2O)_5]_N(ClO_4)_(2n)centre dot 3nH_2O,the first Sm-Ni heterometallic complex of picolinic acid ligand showing novel basket weave topology:Synthesis,structure and magnetics

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