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首页> 外文期刊>Inorganic Chemistry Communications >Novel hetero-polymetallic derivatives of palladium bearing pyridylthioether fragments incorporating a Fe_2(CO)_6 cluster core as ligand
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Novel hetero-polymetallic derivatives of palladium bearing pyridylthioether fragments incorporating a Fe_2(CO)_6 cluster core as ligand

机译:带有Fe_2(CO)_6簇核作为配体的带有吡啶硫基硫醚片段的钯的新型杂多金属衍生物

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摘要

The complexation of poly(pyridylthioether)incorporating a Fe_2(CO)_6 cluster core with palladium derivatives in different oxidation states afforded novel hetero-polymetallic complexes.The synthesis of chelating ligands carrying potentially coordinating nucleophiles and encapsulating metal clusters might represent an important step in the preparation of polymetallic substrates.Moreover,the preparation of composites in which the organic part is constituted by dendri-mers of increasing complexity which however maintain their intrinsic coordinating capability leads to derivatives representing a new class of polymetallic complexes with interesting applications in the field of catalysis [1],molecular recognition [2] and photoactive device engineering [3].
机译:包含Fe_2(CO)_6团簇核的聚(吡啶硫基醚)与不同氧化态的钯衍生物的络合提供了新颖的杂多金属配合物。带有潜在配位亲核试剂和包封金属团簇的螯合配体的合成可能代表着重要的一步。此外,其中有机部分由越来越复杂的树枝状聚合物构成但仍保持其固有配位能力的复合物的制备导致衍生物代表了新型的多金属络合物,在催化领域中具有有趣的应用。 [1],分子识别[2]和光敏器件工程[3]。

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