A novel Lindqvist type polyoxoniobate coordinated to four copper complex moieties:{Nb6O19[Cu(2,2'-bipy)]2[Cu(2,2'-bipy)2]2} centre dot 19H2O

Jing-Ping Wang; Hong-Yu Niu; Jing-Yang Niu

首页> 外文期刊>Inorganic Chemistry Communications >A novel Lindqvist type polyoxoniobate coordinated to four copper complex moieties:{Nb6O19[Cu(2,2'-bipy)]2[Cu(2,2'-bipy)2]2} centre dot 19H2O

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A novel Lindqvist type polyoxoniobate coordinated to four copper complex moieties:{Nb6O19[Cu(2,2'-bipy)]2[Cu(2,2'-bipy)2]2} centre dot 19H2O

机译：新颖的Lindqvist型聚氧杂酸酯与四个铜络合物配位：{Nb6O19 [Cu（2,2'-bipy）] 2 [Cu（2,2'-bipy）2] 2}中心点19H2O

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A novel polyoxoniobate derivative {Nb6O19[Cu(2,2'-bipy)]2[Cu(2,2'-bipy)2]2} centre dot 19H2O1 has been synthesized in aqueous solution and characterized by single-crystal X-ray diffraction method,IR spectroscopy.The structure analysis indicates that the Lindqvist polyoxoniobate [Nb6O19]~(8-) is capped by two divalent Cu atoms through three bridging oxygen atoms on two opposite {Nb3O3} groups and supports two [Cu(2,2'-bipy)2] fragments via the terminal oxygen atoms which are also located in opposite orientations.

机译：在水溶液中合成了新型的聚氧杂酸盐衍生物{Nb6O19 [Cu（2,2'-bipy）] 2 [Cu（2,2'-bipy）2] 2}中心点19H2O1，并通过单晶X射线表征结构分析表明，Lindqvist聚氧杂酸酯[Nb6O19]〜（8-）被两个二价Cu原子通过两个相反的{Nb3O3}基上的三个桥接氧原子所覆盖，并支持两个[Cu（2,2 '-bipy）2]通过同样位于相反方向的末端氧原子断裂。

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来源
《Inorganic Chemistry Communications》 |2008年第1期|共3页
作者
Jing-Ping Wang; Hong-Yu Niu; Jing-Yang Niu;
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正文语种 eng
中图分类无机化学;
关键词
Polyoxometalates; Lindqvist type; Polyoxoniobate; Crystal structure;

机译：多金属氧酸盐;Lindqvist型;多氧铌酸盐;晶体结构;

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1. A novel Lindqvist type polyoxoniobate coordinated to four copper complex moieties:{Nb6O19[Cu(2,2'-bipy)]2[Cu(2,2'-bipy)2]2} centre dot 19H2O [J] . Jing-Ping Wang, Hong-Yu Niu, Jing-Yang Niu Inorganic Chemistry Communications . 2008,第1期

机译：新颖的Lindqvist型聚氧杂酸酯与四个铜络合物配位：{Nb6O19 [Cu（2,2'-bipy）] 2 [Cu（2,2'-bipy）2] 2}中心点19H2O
2. Hydrothermal synthesis and crystal structure of a novel compound supported by alpha-Keggin units [Cu(2,2'-bipy)_2]{AlW_(11)~(VI)W~vO_(40)[Cu(2,2'-bipy)_2]_2} centre dot 2H_2O [J] . Jingping Wang, Yue Shen, Jingyang Niu Journal of Coordination Chemistry . 2006,第9期

机译：α-Keggin单元[Cu（2,2'-bipy）_2] {AlW_（11）〜（VI）W〜vO_（40）[Cu（2,2'- bipy）_2] _2}中心点2H_2O
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机译：苯并1,2-二氧乙酸（BDOAH（2））-[CU（BDOA）（C6H5NH2）（2）] 2C6H5NH2和[CU（BDOA）（（BIPY）（4）] BDOA-CENTER-DOT-8.66H（2）O（C6H5NH2-苯胺，BIPY = 2,2'-BIPYRIDINE）
4. Study Of Nature Of Structural Defects In A Prussian Blue Type Cu_(0.73)Mn_(0.77)Fe(CN)_(6)(centre dot)zH_(2)O Molecular Magnet [C] . Amit Kumar, S. M. Yusuf, J. V. Yakhmi International Conference on Physics of Emerging Functional Materials . 2010

机译：普鲁士蓝型Cu_（0.73）Mn_（0.77）Fe（CN）_（6）（中心点）ZH_（2）O分子磁体的结构缺陷性质研究
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6. Synthesis, Superoxide Dismutase Mimetic and Anticancer Activities of Metal Complexes of 2,2-Dimethylpentanedioic Acid(2dmepdaH2) and 3,3-Dimethylpentanedioic acid(3dmepdaH2): X-Ray Crystal Structures of [Cu(3dmepda)(bipy)]2· 6H2O and [Cu(2dmepda)(bipy)(EtOH)]2· 4EtOH (bipy = 2,2′Bipyridine) [O] . Devereux, Michael, McCann, Malachy, O'Shea, Denis, 2006

机译：2,2-二甲基戊二酸（2dmepdaH2）和3,3-二甲基戊二酸（3dmepdaH2）的金属配合物的合成，超氧化物歧化酶模拟和抗癌活性：[Cu（3dmepda）（bipy）] 2·6H2O的X射线晶体结构和[Cu（2dmepda）（bipy）（EtOH）] 2·4EtOH （Bipy = 2,2'联吡啶）

A novel Lindqvist type polyoxoniobate coordinated to four copper complex moieties:{Nb6O19[Cu(2,2'-bipy)]2[Cu(2,2'-bipy)2]2} centre dot 19H2O

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