The reaction of a potentially N2S-donor bis[benzo(thiazole/imidazole)] with the fac-[Re(CO)3]~+ and cis-[ReO2]~+ cores

T.I.A. Gerber; K.C. Potgieter; P. Mayer

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The reaction of a potentially N2S-donor bis[benzo(thiazole/imidazole)] with the fac-[Re(CO)3]~+ and cis-[ReO2]~+ cores

机译：潜在的N2S供体双[苯并（噻唑/咪唑）]与fac- [Re（CO）3]〜+和cis- [ReO2]〜+核的反应

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The reactions of bis(benzothiazol-2-ylethyI)sulfide (bts) and its benzimidazole analogue (btn), both with a N2S-donor atom set, with [Re(CO)5Br] and cis-[ReO2I(PPh3)2] were studied. The X-ray crystal structure of fac-[Re(CO)3(bts)Br] shows that bts acts as a bidentate NS-donor ligand, with a free uncoordinated benzothiazole group. With rhenium(V) the dimer (μ-O)2[Re2O2(btn)2]I2 was isolated, in which btn acts as a tridentate N2S chelate to each metal centre. Each oxo-bridge is unsymmetrical, with unequal Re-0 distances.

机译：双（苯并噻唑-2-甲基）硫化物（bts）及其苯并咪唑类似物（btn）均具有N 2 S-给体原子组，与[Re（CO）5Br]和顺式[ReO2I（PPh3）2]反应被研究了。 fac- [Re（CO）3（bts）Br]的X射线晶体结构表明bts充当双齿NS供体配体，带有游离的未配位苯并噻唑基团。用rh（V）分离出二聚体（μ-O）2 [Re2O2（btn）2] I2，其中btn充当每个金属中心的三齿N2S螯合物。每个氧桥不对称，Re-0距离不相等。

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《Inorganic Chemistry Communications》 |2011年第7期|共4页
作者
T.I.A. Gerber; K.C. Potgieter; P. Mayer;
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正文语种 eng
中图分类无机化学;
关键词
Rhenium(I); Tridentate benzoxazole; Di-oxo bridged rhenium(V);

机译：hen（I）;Tr苯并恶唑;二氧代桥联（（V）;

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1. The reaction of a potentially N2S-donor bis[benzo(thiazole/imidazole)] with the fac-[Re(CO)3]~+ and cis-[ReO2]~+ cores [J] . T.I.A. Gerber, K.C. Potgieter, P. Mayer Inorganic Chemistry Communications . 2011,第7期

机译：潜在的N2S供体双[苯并（噻唑/咪唑）]与fac- [Re（CO）3]〜+和cis- [ReO2]〜+核的反应
2. Copper-catalyzed one-pot coupling reactions of aldehydes (ketones), tosylhydrazide and 2-amino(benzo)thiazoles: An efficient strategy for the synthesis of N-alkylated (benzo)thiazoles [J] . Xie Zengyang, Chen Ruijiao, Ma Mingfang, Applied Organometallic Chemistry . 2019,第10期

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The reaction of a potentially N2S-donor bis[benzo(thiazole/imidazole)] with the fac-[Re(CO)3]~+ and cis-[ReO2]~+ cores

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