Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction

Bernadette S.Creaven; Mary F.Mahon; John McGinley; Ann-Marie Moore

首页> 外文期刊>Inorganic Chemistry Communications >Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction

【24h】

Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction

机译：具有意想不到的Cu-H相互作用的三齿N供体配体的铜（II）配合物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The new pyridine-amine ligand,meophdpa (bis(dipyridylmethyl)-4-methoxyaniline) was synthesised and reacted with copper(II) per-chlorate.The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site,with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion,as well as a chloride and a water molecule.The sixth coordination site was,unexpectedly,occupied by a phenyl ring hydrogen atom.

机译：合成了一种新的吡啶-胺配体meophdpa（双（二吡啶基甲基）-4-甲氧基苯胺），并与高氯酸铜（II）反应。生成的配合物的X射线晶体结构显示出一个单体铜（II）位，铜以相对不寻常的子午方式键合到三个配体氮上，以及氯化物和水分子。第六个配位点出乎意料地被苯环氢原子占据。

著录项

来源
《Inorganic Chemistry Communications》 |2006年第2期|共4页
作者
Bernadette S.Creaven; Mary F.Mahon; John McGinley; Ann-Marie Moore;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Tridentate pyridine-amine ligand; Synthesis; Copper(II) complex; X-ray crystal structure;

机译：三齿吡啶-胺配体;合成;铜（II）配合物;X射线晶体结构;

相似文献

外文文献
中文文献
专利

1. Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction [J] . Bernadette S.Creaven, Mary F.Mahon, John McGinley, Inorganic Chemistry Communications . 2006,第2期

机译：具有意想不到的Cu-H相互作用的三齿N供体配体的铜（II）配合物
2. Hexaeyanochromates(HI) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of ({Cu(ept)}3{Co(CN)6}2)·H2O (ept = N-(2-aminoethyl)-1,3-propandiamine) [J] . K. Mamulova Kutlakova, Z. Smekal, A. Neels Polish Journal of Chemistry . 2009,第10期

机译：带有三齿和四齿N-给体配体的铜（II）的六氰基铬酸盐（HI）和六氰基钴酸盐（III）。（{Cu（ept）} 3 {Co（CN）6} 2）·H2O（ept = N-（2-氨乙基）-1,3-丙二胺）的晶体结构
3. Antiproliferative activity of copper(II) glutamine complexes with N,N-donor ligands: Synthesis, characterization, potentiometric studies and DNA/BSA interactions [J] . Kiraz Sirem, Inci Duygu, Aydin Rahmiye, Journal of Molecular Structure . 2019,第期

机译：铜（II）谷氨酰胺配合物的抗增殖活性N，N-供体配体：合成，表征，电位研究和DNA / BSA相互作用
4. XAFS Study of the Ferro- and Antiferromagnetic Binuclear Copper(II) Complexes of Azomethine Based Tridentate Ligands [C] . Valery G. Vlasenko, Igor S. Vasilchenko, Irina V. Pirog, International Conference on X-ray Absorption Fine Structure . 2007

机译：XAFS研究氮杂甲胺基三季配体的铁铁和反铁磁性铜铜（II）复合物
5. Relationship between ligand structure and reactivity for copper(II) complex mediated hydrolysis of phosphate diesters, carboxylic esters, and amides. Part~I. Hydrolysis of phosphate diesters promoted by copper(II) complexes. Part~II. Hydrolysis of carboxylic esters and amides catalyzed by copper(II) complexes. [D] . Jubian, Vrej. 1991

机译：铜（II）配合物介导的磷酸二酯，羧酸酯和酰胺水解的配体结构与反应性之间的关系。第一部分铜（II）配合物促进的磷酸二酯的水解。第二部分铜（II）配合物催化的羧酸酯和酰胺的水解。
6. Norfloxacin and N-Donor Mixed-Ligand Copper(II) Complexes: Synthesis Albumin Interaction and Anti-Trypanosoma cruzi Activity [O] . Darliane A. Martins, Ligiane R. Gouvea, Gabriel S. Vignoli Muniz, 2016

机译：诺氟沙星和N-供体混合配体铜（II）配合物：合成白蛋白相互作用和抗锥虫。
7. Cationic and neutral copper(I) iodide cluster MOFs derived from tridentate N-donor functionalized P(V) ligands: synthesis, structure and photophysical properties [O] . Ashok Yadav, Mahesh S Deshmukh, Ramamoorthy Boomishankar 2017

机译：阳离子和中性铜（I）碘化物簇MOF衍生自三叉戟N-供体官能化P（V）配体：合成，结构和光物理性质

Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction

摘要

著录项

相似文献

相关主题

期刊订阅