Synthesis,crystal structure and magnetic properties of 1D chain Cu(II)complex with the single-mu-chloro bridging

Xi-Li Li; Bao-Lin Liu; You Song

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Synthesis,crystal structure and magnetic properties of 1D chain Cu(II)complex with the single-mu-chloro bridging

机译：单μ氯桥联的一维链Cu（II）配合物的合成，晶体结构和磁性

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Using chiral bidentate ligand containing N-donors L_(RR)(-)-4,5 pinene bipyridine,a 1D chain single-mu-chloro bridged Cu(II)complex(CuL_(RR)Cl2)_n(1)was synthesized in methanol and characterized by X-ray crystallography and magnetic measurements.X-ray analysis shows that 1 crystallizes in space group Pbca of orthorhombic.The structure of 1 is a neutral,one-dimensional infinite chain polymer.The magnetic investigations demonstrate that complex 1 exhibits intrachain Cu(II)-Cu(II)antiferromagnetic coupling with J=-2.276 cm~(-1).

机译：使用含有N-给体L_（RR）（-）-4,5 pin烯联吡啶的手性双齿配体，合成了1D链单mu-氯桥联的Cu（II）络合物（CuL_（RR）Cl2）_n（1）。甲醇，经X射线晶体学和磁性测量表征.X射线分析表明1在正交晶的空间群Pbca中结晶.1的结构为中性，一维无限链聚合物。磁性研究表明，配合物1表现出J = -2.276 cm〜（-1）的链内Cu（II）-Cu（II）反铁磁耦合。

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《Inorganic Chemistry Communications》 |2008年第9期|共3页
作者
Xi-Li Li; Bao-Lin Liu; You Song;
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正文语种 eng
中图分类无机化学;
关键词
Chain; Chloro bridge; Copper; Crystal structure; Magnetic property;

机译：链;氯桥;铜;晶体结构;磁性能;

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1. Synthesis,crystal structure and magnetic properties of 1D chain Cu(II)complex with the single-mu-chloro bridging [J] . Xi-Li Li, Bao-Lin Liu, You Song Inorganic Chemistry Communications . 2008,第9期

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Synthesis,crystal structure and magnetic properties of 1D chain Cu(II)complex with the single-mu-chloro bridging

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