A new three-dimensional cobalt(II) coordination polymer based on biphenyl-2,2',6,6'-tetracarboxylic acid and 1,2,4-triazole: Synthesis, crystal structure and magnetic properties

Lin Cheng; Jian-Quan Wang; Shao-Hua Gou

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A new three-dimensional cobalt(II) coordination polymer based on biphenyl-2,2',6,6'-tetracarboxylic acid and 1,2,4-triazole: Synthesis, crystal structure and magnetic properties

机译：基于联苯-2,2'，6,6'-四羧酸和1,2,4-三唑的新型三维钴（II）配位聚合物：合成，晶体结构和磁性

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A new three-dimensional coordination polymer with the formula [Co(bta)_(0.5)(Htz)(H2O)]_n (1) (H4bta = biphenyl-2,2',6,6'-tetracarboxylic acid and Htz =1,2,4-triazole), has been hydrothermally synthesized and structurally characterized. The structure of 1 can be considered as two-dimensional [Co(bta)(H2O)]_n layers, consisting of one-dimensional [Co(COO)]_n chains, which are separated by bta ligands, and neutral Htz pillars. The variable temperature magnetic property study indicates that there is a weak antiferromagnetic coupling interaction between Co(II) ions, which mainly arises from the antiferromagnetic coupling interaction in the one-dimensional [Co(COO)]_n chains through syn-anti carboxylate bridges.

机译：一种新的具有[Co（bta）_（0.5）（Htz）（H2O）] _ n（1）式的三维配位聚合物（H4bta =联苯-2,2'，6,6'-四羧酸，Htz = 1,2,4-三唑）已经水热合成并进行了结构表征。 1的结构可以看作是二维[Co（bta）（H2O）] _ n层，由一维[Co（COO）] _ n链（由bta配体分隔）和中性的Htz柱组成。可变温度磁性能研究表明，Co（II）离子之间存在弱的反铁磁耦合相互作用，这主要是由于一维[Co（COO）] _ n链通过顺-反羧酸盐桥的反铁磁耦合相互作用引起的。

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来源
《Inorganic Chemistry Communications》 |2011年第1期|共4页
作者
Lin Cheng; Jian-Quan Wang; Shao-Hua Gou;
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正文语种 eng
中图分类无机化学;
关键词
Biphenyl-2; 2'; 6; 6'-tetracarboxylate; 1; 2; 4-Triazole; Co(II) complex; Antiferromagnetic;

机译：联苯-2;2';6;6'-四羧酸盐;1;2;4-三唑;Co（II）络合物;反铁磁;

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1. A new three-dimensional cobalt(II) coordination polymer based on biphenyl-2,2',6,6'-tetracarboxylic acid and 1,2,4-triazole: Synthesis, crystal structure and magnetic properties [J] . Lin Cheng, Jian-Quan Wang, Shao-Hua Gou Inorganic Chemistry Communications . 2011,第1期

机译：基于联苯-2,2'，6,6'-四羧酸和1,2,4-三唑的新型三维钴（II）配位聚合物：合成，晶体结构和磁性
2. Synthesis, Crystal Structure, and Magnetic Properties of Two Manganese(II) and Cobalt(II) Coordination Polymers Based on Biphenyl-3,3',4,4'-tetracarboxylic Acid [J] . Juan Song, Hui-Ming Shu, Huai-Ming Hu, Zeitschrift fur Anorganische und Allgemeine Chemie . 2014,第7期

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8. Inorganic Coordination Polymers. Part XIX. Steric Effects of Hydrocarbon Side Groups on the Structure and Properties of Zinc(II),Cobalt(II),Manganese(II),Nickel(II) and Copper(II) Bis(Phosphinates). [R] . gillman, h. d. eichelberger, j. l. 1975

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A new three-dimensional cobalt(II) coordination polymer based on biphenyl-2,2',6,6'-tetracarboxylic acid and 1,2,4-triazole: Synthesis, crystal structure and magnetic properties

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