A Fe_(17) cluster with S = 35/2 ground state: Synthesis, structure, and magnetic properties

Zhi-Guo Gu; Bao-Xiang Wang; Jing-Jing Na

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A Fe_(17) cluster with S = 35/2 ground state: Synthesis, structure, and magnetic properties

机译：具有S = 35/2基态的Fe_（17）团簇：合成，结构和磁性

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A new polyiron complex [Fe_(17)(OH)7O_(11)(O2CPh)_(20)(N3)2]·4H2O-10MeCN (1), with compact [Fe_(17)OH7O_(11)] core encapsulated by twenty benzoate anions and two end-on (EO) azido ligands has been synthesized and structurally characterized. Intramolecular antiferromagnetic couplings are observed for 1 and it has S = 35/2 ground state which was confirmed by magnetic measurements and Mossbauer spectra.

机译：一种新型多铁配合物[Fe_（17）（OH）7O_（11）（O2CPh）_（20）（N3）2]·4H2O-10MeCN（1），并封装了紧凑的[Fe_（17）OH7O_（11）]核由二十个苯甲酸酯阴离子和两个端基（EO）叠氮基配体合成并进行了结构表征。观察到分子内反铁磁偶合为1，其具有S = 35/2基态，这通过磁测量和Mossbauer光谱得到了证实。

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来源
《Inorganic Chemistry Communications》 |2011年第6期|共4页
作者
Zhi-Guo Gu; Bao-Xiang Wang; Jing-Jing Na;
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正文语种 eng
中图分类无机化学;
关键词
Iron(III); Oxo/azido-bridged cluster; Self-assembly; Benzoate ligand;

机译：铁（III）;氧/叠氮桥簇;自组装;苯甲酸酯配体;

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1. A Fe_(17) cluster with S = 35/2 ground state: Synthesis, structure, and magnetic properties [J] . Zhi-Guo Gu, Bao-Xiang Wang, Jing-Jing Na Inorganic Chemistry Communications . 2011,第6期

机译：具有S = 35/2基态的Fe_（17）团簇：合成，结构和磁性
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A Fe_(17) cluster with S = 35/2 ground state: Synthesis, structure, and magnetic properties

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