Synthesis and characterization of nickel(II) and copper(II) complexes with a tetramethyltetraaza macrocycle containing 2-pyridylmethyl pendant arms

Ki-Young Choi; Hye-Ok Lee; Yong-Son Kim; Kang-Moon Chun; Kyu-Chul Lee; Suk-Nam Choi; Choon-Pyo Hong; Young-You Kim

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Synthesis and characterization of nickel(II) and copper(II) complexes with a tetramethyltetraaza macrocycle containing 2-pyridylmethyl pendant arms

机译：含2-吡啶基甲基侧链的四甲基四氮杂大环镍（II）和铜（II）配合物的合成与表征

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The complexes [Ni(L~2)](ClO_40)_2·H_2O (1) and [Cu(L~2)]Cl_2·4H_2O (2) have been synthesized and characterized by X-ray crystallography, electronic absorption and cyclic voltammetry. The crystal structure of 1 reveals a distorted octahedral geometry with four nitrogen atoms of the macrocycle and two nitrogen atoms of the pendant pyridylmethyl group. The structure of 2 shows that the complex is centrosymmetric and the metal center has a tetragonally distored octahedral environment. The electronic spectra and electrochemical behaviors of the complexes are significantly affected by the presence of the pendant arms.

机译：合成了配合物[Ni（L〜2）]（ClO_40）_2·H_2O（1）和[Cu（L〜2）] Cl_2·4H_2O（2），并通过X射线晶体学，电子吸收和循环伏安法对其进行了表征。。 1的晶体结构显示出扭曲的八面体几何形状，其中大环上有四个氮原子，而吡啶甲基甲基侧基上有两个氮原子。 2的结构表明，该络合物是中心对称的，并且金属中心具有四边形扭曲的八面体环境。悬臂的存在极大地影响了配合物的电子光谱和电化学行为。

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来源
《Inorganic Chemistry Communications》 |2002年第7期|共5页
作者
Ki-Young Choi; Hye-Ok Lee; Yong-Son Kim; Kang-Moon Chun; Kyu-Chul Lee; Suk-Nam Choi; Choon-Pyo Hong; Young-You Kim;
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正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
crystal structures; Di-N-pyridylmethylated macrocycle; nickel(II) complex; copper(II) complex;

机译：晶体结构;二-N-吡啶甲基化大环;镍（II）配合物;铜（II）配合物;

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1. Synthesis and characterization of nickel(II) and copper(II) complexes with a tetramethyltetraaza macrocycle containing 2-pyridylmethyl pendant arms [J] . Ki-Young Choi, Hye-Ok Lee, Yong-Son Kim, Inorganic Chemistry Communications . 2002,第7期

机译：含2-吡啶基甲基侧链的四甲基四氮杂大环镍（II）和铜（II）配合物的合成与表征
2. Synthesis and properties of a tetraaza macrocyclic ligand containing 2-pyridylmethyl pendant arms and its copper(II) and nickel(II) complexes: crystal structure of the copper(II) complex [J] . Kang SG., Jeong JH., Kim SJ. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第18期

机译：含2-吡啶基甲基侧链的四氮杂大环配体及其铜（II）和镍（II）配合物的合成与性能：铜（II）配合物的晶体结构
3. Synthesis and Properties of Tetraaza Macrocycles Containing Two 3-Pyridylmethyl, 4-Pyridylmethyl, or Phenylmethyl Pendant Arms and Their Nickel(II) and Copper(II) Complexes: Effects of the Pendant Arms on the Complex Formation Reaction [J] . Seong-Jin Kim, Shin-Geol Kang Bulletin of the Korean Chemical Society . 2003,第3期

机译：包含两个3-吡啶基甲基，4-吡啶基甲基或苯甲基甲基侧链及其镍（II）和铜（II）配合物的四环大环的合成及性质：侧链对配合物形成反应的影响
4. Chitosan- Copper(II) , Zinc(II) and Ferric(II) Complexes as Antimicrobial Agent: Synthesis, Characterization and Structure- Activity Study [C] . Xiaohui Wang, Yumin Du, Fei Huang Polymeric Materials: Science Engineering Symposia . 2005

机译：壳聚糖 - 铜（II），锌（II）和铁（II）复合物作为抗微生物剂：合成，表征和结构 - 活性研究
5. Nickel, copper, and iron complexes of aminopyridine macrocycles with a modifiable pendant aminopropyl arm. [D] . Herrera Gutierrez, Aida Margarita. 2003

机译：氨基吡啶大环的镍，铜和铁配合物，具有可修饰的氨基丙基侧基臂。
6. Synthesis structural studies and oxidation catalysis of the manganese(II) iron(II) and copper(II) complexes of a 2-pyridylmethyl pendant armed side-bridged cyclam [O] . Anthony D. Shircliff, Kevin R. Wilson, Desiray J. Cannon, -1

机译：2-吡啶基甲基悬挂侧桥环己酰胺的锰（II）铁（II）和铜（II）配合物的合成结构研究和氧化催化
7. Synthesis, structural studies, and oxidation catalysis of the manganese(II), iron(II), and copper(II) complexes of a 2-pyridylmethyl pendant armed side-bridged cyclam [O] . Anthony D. Shircliff, Kevin R. Wilson, Desiray J. Cannon-Smith, 2015

机译：合成，结构研究和锰（II），铁（II）和铜（II）复合物的2-吡啶基甲基吊坠臂侧桥旋转旋风分离症的合成，结构研究和氧化催化剂
8. Synthesis and Properties of Homonuclear Dimetallic Nickel(II), Copper(II) and Zinc(II) Complexes of p-Xylenediyl and 2-Butynediyl-Bridged Dicyclenes. [R] . Crane, C. G., Burrows, C. J. 1993

机译：对二甲苯二基和2-丁二基桥连二环的双核二聚镍（II），铜（II）和锌（II）配合物的合成和性质。

Synthesis and characterization of nickel(II) and copper(II) complexes with a tetramethyltetraaza macrocycle containing 2-pyridylmethyl pendant arms

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