IN-III-PHTHALOCYANINES - SYNTHESIS, PROPERTIES, AND CRYSTAL STRUCTURE OF TETRA(N-BUTYL)AMMONIUM-CIS-DI(NITRITO-O,O')PHTHALOCYANINATO(2-)INDATE(III) German

Assmann B.; Homborg H.; Ostendorp G.

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IN-III-PHTHALOCYANINES - SYNTHESIS, PROPERTIES, AND CRYSTAL STRUCTURE OF TETRA(N-BUTYL)AMMONIUM-CIS-DI(NITRITO-O,O')PHTHALOCYANINATO(2-)INDATE(III) German

机译：IN-III-PHTHALOCYANINES - TETRA（N-BUTYL）AMMONIUM-CIS-DI（NITRITO-O，O'）PHTHALOCYANINATO（2-）INDATE（III）的合成、性质和晶体结构德语

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In(Cl)Pc(2-) reacts with ((n)Bu(4)N)NO2 in acetone yielding green-blue ((n)Bu(4)N)(cis)In(NO2)(2)Pc(2-), which crystallizes in the monoclinic space group P2(1)/n (No. 14). Both nitrite anions are coordinated as chelating nitrito-O,O'(NO2) ligands to In-III in cia-geometry. Consequently In-III is octa-coordinated within a distorted ''quadratic'' antiprism and directed towards the Pc(2-)-Ligand. One of the NO2 Ligands has equivalent N-O bonds similar to free nitrite, while the other has asymmetric N-O bonds. Both (In,O,N,O) rings are approximately planar with a dihedral angle of 80 degrees. The Pc(2-) ligand is distorted in an asymmetrically convex manner. Partially overlapping pairs of Pc(2-) ligands related by an inversion center form double layers, which are separated by layers containing the ((n)Bu(4)N)(+) cations. The cyclic voltammogram shows three electrode processes, which are assigned to the redox pairs: Pc(3-)/Pc(2-) (-0.94 V) < In-I/In-III (-0.78 V) < Pc(2-)/Pc(-) (0.64 V). The UV-VIS-NIR spectra and vibrational spectra are discussed. References: 52

机译：[In（Cl）Pc（2-）] 在丙酮中与（（n）Bu（4）N）NO2 反应生成绿蓝色（（n）Bu（4）N）（顺式）[In（NO2）（2）Pc（2-）]，其在单斜晶系空间群 P2（1）/n （No. 14）中结晶。两种亚硝酸盐阴离子在cia几何形状中作为螯合nitrito-O，O'（NO2）配体配位到In-III。因此，In-III在扭曲的“二次”反棱镜内是八进制配位的，并指向Pc（2-）-配体。其中一种 NO2 配体具有类似于游离亚硝酸盐的等效 N-O 键，而另一种具有不对称的 N-O 键。两个（In，O，N，O）环近似平面，二面角为 80 度。Pc（2-）配体以不对称凸的方式扭曲。由反转中心相关的部分重叠的Pc（2-）配体对形成双层，双层由含有（（n）Bu（4）N）（+）阳离子的层隔开。循环伏安图显示了分配给氧化还原对的三个电极过程：Pc（3-）/Pc（2-）（-0.94 V） < In-I/In-III （-0.78 V） < Pc（2-）/Pc（-）（0.64 V）。讨论了紫外-可见-近红外光谱和振动光谱。[参考文献： 52]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1995年第10期|1708-1714|共7页
作者
Assmann B.; Homborg H.; Ostendorp G.;
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CHRISTIAN ALBRECHTS UNIV KIEL INST ANORGAN CHEM OLSHAUSENSTR 40 OHP 6-7 D-24098 KIEL GERMANY;

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中图分类化学;
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Indium(iii) phthalocyanines; nitrito-o; o' complexes; Cyclic voltammetry; Optical spectra; Vibrational spectra; Crystal structure; Metal phthalocyanines; Derivatives; Nitrite; Metallophthalocyanines; Porphyrins; Iron(iii); Spectra;

机译：酞菁铟（iii）;氮基-O;O' 复合物;循环伏安法;光谱;振动光谱;晶体结构;金属酞菁;衍生品;亚硝酸盐;金属氟芥花菁;卟啉;铁（iii）;光谱;

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IN-III-PHTHALOCYANINES - SYNTHESIS, PROPERTIES, AND CRYSTAL STRUCTURE OF TETRA(N-BUTYL)AMMONIUM-CIS-DI(NITRITO-O,O')PHTHALOCYANINATO(2-)INDATE(III) German

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