A NEW OXOPHOSPHATE(IV/III) ANION - PREPARATION AND CRYSTAL STRUCTURE OF NA6P4O10-CENTER-DOT-2H2O

Hagen S.; Jansen M.

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A NEW OXOPHOSPHATE(IV/III) ANION - PREPARATION AND CRYSTAL STRUCTURE OF NA6P4O10-CENTER-DOT-2H2O

机译：一种新的氧磷酸盐（IV/III）阴离子-NA6P4O10中心-点-2H2O的制备及晶体结构

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A new oxophosphate anion, P4O106-, was obtained by cleavage and simultaneous oxidation of the cyclo-hexaphosphate(III) anion in a solution of aqueous ammonia and ethanol. With sodium it forms a salt with the composition Na(6)P(4)O(10)(.)2H(2)O. The crystal structure has been determined by single crystal X-ray diffraction (3745 diffractometer data), the cell constants were obtained from X-ray powder data: space group P (

机译：将环六磷酸（III）阴离子在氨水和乙醇溶液中裂解并同时氧化，制得了一种新的氧磷酸根阴离子P4O106-。与钠形成盐，其组成为Na（6）P（4）O（10）（。2H（2）O.晶体结构已通过单晶X射线衍射确定（3745个衍射仪数据），从X射线粉末数据中获得电池常数：空间群P（

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1995年第1期|7-13|共7页
作者
Hagen S.; Jansen M.;
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作者单位

UNIV BONN INST ANORGAN CHEM GERHARD DOMAGK STR 1 D-53121 BONN GERMANY;

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原文格式 PDF
正文语种英语
中图分类化学;
关键词
Sodium phosphate; Oxophosphate (iv/iii); Crystal structure; P-31-nmr;

机译：磷酸钠;氧磷酸盐（iv/iii）;晶体结构;P-31核磁共振;

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1. ChemInform Abstract: A New Oxophosphate(IV/III) Anion ‐ Preparation and Crystal Structure of Na6P4O10×2 H2O. [J] . S. HAGEN, M. JANSEN Chem Inform . 1995,第20期

机译：ChemInform Abstract: A New Oxophosphate(IV/III) Anion ‐ Preparation and Crystal Structure of Na6P4O10×2 H2O.
2. ChemInform Abstract: Thermal Behavior and Crystal Chemistry of Anhydrous Phosphates. Part 12. Preparation and Chemical Vapor Transport of Mixed Valent Titanium( III,IV)‐phosphates. With a Note on the Crystal Structure of Titanium( IV)‐orthophosphate Ti5P4O20. [J] . F. REINAUER, R. GLAUM, R. GRUEHN Chem Inform . 1995,第7期

机译：ChemInform Abstract: Thermal Behavior and Crystal Chemistry of Anhydrous Phosphates. Part 12. Preparation and Chemical Vapor Transport of Mixed Valent Titanium( III,IV)‐phosphates. With a Note on the Crystal Structure of Titanium( IV)‐orthophosphate Ti5P4O20.
3. ChemInform Abstract: Dimeric and Polymeric Pnictidostannate(IV) Anions — Preparation and Crystal Structures of Na2K3SnP3, Na2Cs3SnP3 and Na2K3SnBi3. [J] . M. ASBRAND, B. EISENMANN, H. ENGELHARDTU. ROESSLER Chem Inform . 1998,第31期

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A NEW OXOPHOSPHATE(IV/III) ANION - PREPARATION AND CRYSTAL STRUCTURE OF NA6P4O10-CENTER-DOT-2H2O

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