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MULTIDIMENSIONAL IDENTIFICATION OF CHEMICAL WARFARE AGENTS USING SHAPED FEMTOSECOND PULSES

机译:使用成形的飞秒圆锥脉冲对化学战剂进行多维识别

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摘要

Detection and identification of chemical warfare simulants based on multidimensional phase shaped femtosecond laser pulses coupled to mass spectrometry (MS) is demonstrated. The presented approach is based on binary phase shaping (BPS) and aims to improve the accuracy and precision required for security applications. It is based on multiphoton intrapulse interference of femtosecond laser pulses. Spectra retrieved by applying n-differently shaped pulses represent n-dimensions of the analysis. We present a multidimensional technique for detection and identification of analogues to chemical agents and mixtures in real-time. Experimental results for dimethyl phosphate, pyridine, and three isomers of nitrotoluene are presented.
机译:演示了基于多维相形飞秒激光脉冲与质谱(MS)耦合的化学战模拟物的检测和识别。提出的方法基于二进制相位整形(BPS),旨在提高安全应用程序所需的准确性和精度。它基于飞秒激光脉冲的多光子脉冲内干扰。通过施加n个不同形状的脉冲获得的光谱表示分析的n维。我们提出了一种实时检测和识别化学试剂和混合物类似物的多维技术。给出了磷酸二甲酯,吡啶和硝基甲苯的三种异构体的实验结果。

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