Composition and size dependent methane dehydrogenation on binary gold-palladium clusters in Memoriam Dr. Detlef Schr?der.

Lang S.M.; Frank A.; Bernhardt T.M.

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Composition and size dependent methane dehydrogenation on binary gold-palladium clusters in Memoriam Dr. Detlef Schr?der.

机译：Memoriam。Detlef Schr？der博士对二元金-钯簇上甲烷的脱氢组成和尺寸的依赖性。

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Methane adsorption and possible dehydrogenation mediated by the free gold-palladium clusters Au_2Pd~+, AuPd_2~ +, and Au_2Pd_2~ + have been investigated in an ion trap experiment under multi-collision conditions. Temperature dependent kinetic measurements identify the palladium-rich AuPd_ 2~ + as the only one among these clusters which is able to dehydrogenate methane. The comparison with previously measured reactions of the bare gold Au_n~ + (n = 2-4) as well as the bare palladium Pd_m~ + (m = 2-4) clusters allows to obtain insights into cluster size and composition dependent reaction mechanisms, kinetics, and methane binding energies.

机译：在多碰撞条件下的离子阱实验中研究了游离金-钯簇Au_2Pd〜+，AuPd_2〜+和Au_2Pd_2〜+介导的甲烷吸附和可能的脱氢。温度相关的动力学测量结果表明，富钯的AuPd_2〜+是这些簇中唯一能够使甲烷脱氢的簇。与裸金Au_n〜+（n = 2-4）和裸钯Pd_m〜+（m = 2-4）簇的先前测量的反应进行比较，可以洞悉簇的大小和与组成有关的反应机理，动力学和甲烷结合能。

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《International journal of mass spectrometry》 |2013年第null期|共7页
作者
Lang S.M.; Frank A.; Bernhardt T.M.;
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正文语种 eng
中图分类光化学分析法（光谱分析法）;
关键词
Alloy clusters; Gas phase reaction kinetics; Gold; Ion trap mass spectrometry; Palladium;

机译：合金团簇;气相反应动力学;金;离子阱质谱;钯;

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1. Composition and size dependent methane dehydrogenation on binary gold-palladium clusters in Memoriam Dr. Detlef Schr?der. [J] . Lang S.M., Frank A., Bernhardt T.M. International journal of mass spectrometry . 2013,第Null期

机译：Memoriam。Detlef Schr？der博士对二元金-钯簇上甲烷的脱氢组成和尺寸的依赖性。
2. Electron capture dissociation of a self-assembled tetranuclear metallosupramolecular complex in the gas phase in memoriam of Dr. Detlef Schr?der. [J] . Hovorka R., Engeser M., Lützen A. International journal of mass spectrometry . 2013,第Null期

机译：在Detlef Schr？der博士的遗忘中，气相中自组装的四核金属超分子复合物的电子捕获解离。
3. Counter-ion and solvent effects in electrospray ionization of solutions of alkali metal and quaternary ammonium salts in Memoriam Detlef Schr?der. [J] . Koszinowski K., Lissy F. International journal of mass spectrometry . 2013,第Null期

机译：Memoriam Detlef Schrder中碱金属和季铵盐溶液电喷雾电离中的反离子和溶剂效应。
4. SIZE-AND SUPPORT-DEPENDENT ELECTRONIC AND CATALYTIC PROPERTIES OF SIZE SELECTED CLUSTER CATALYSTS ON METHANATION OF CO: A COMBINED GIXAS, GISAXS AND TPRX STUDY [C] . Sungsik Lee, Byeongdu Lee, Sonke Seifert ACS National Meeting Exhibition . 2015

机译：甲烷化甲烷化的尺寸和依赖性电子和催化性能的尺寸和依赖性簇催化剂催化剂：吉西组合，吉萨斯和TPRX研究
5. TEMPERATURE PROGRAMMED DECOMPOSITION, METHANATION, AND FISCHER-TROPSCH STUDIES WITH SUPPORTED RUTHENIUM CARBONYL CLUSTER COMPLEXES. [D] . MATRANA, BARRY ALLEN. 1982

机译：温度程序化的分解，甲烷化和费歇尔-托普希斯研究，并采用了钌羰基团簇配合物。
6. Relative Efficiency of Unequal Versus Equal Cluster Sizes for the Nonparametric Weighted Sign Test Estimators in Clustered Binary Data [O] . Chul Ahn, Fan Hu, Seung-Chun Lee -1

机译：在聚类二进制数据中非参数加权标志测试估计的非相等群集的相对效率
7. Synthesis of bis- and tris(indolyl)methanes catalyzed by an inorganic nano-sized catalyst followed by dehydrogenation to hyperconjugated products [O] . Khorshidi Alireza, Shariati Shahab, Abootalebi Masoomeh 2016

机译：由无机纳米催化剂催化合成双 - 和三（吲哚基）甲烷，然后脱氢成超共轭产物

Composition and size dependent methane dehydrogenation on binary gold-palladium clusters in Memoriam Dr. Detlef Schr?der.

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