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Nano-sized molybdenum powder

机译:纳米钼粉

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摘要

In a further contribution devoted to this important refractory metal, Sunil Jha of the Climax Molybdenum Company, Sahuarita, Arizona, introduced a significantly different process for making ultrafine molybdenum powder. Now being produced in commercial quantities, the high specific surface area of this product enables fully dense parts to be obtained at lower sintering temperatures. It also makes processing of Mo/Cu and Mo/Ag more cost-effective and the alloys easier to fabricate into electronic components, such as heat sinks and electrical contacts. Agglomerated to improve handling, the ultrafine powder can also be used in MIM feedstocks. In principle, the production sequence for nano Mo is much the same as that described in the previous paper, but in practice it is noticeably different. The patented process involves quenching MoO_3 vapours to form nano molybdenum trioxide (NTO) particles of 50-100 nm grain size (Fig. 25). Surface area of NTO approaches 60 m~2/g and its apparent density is in the range 0.11-0.14 g/cm~3.
机译:为了进一步致力于这种重要的难熔金属,亚利桑那州萨瓦里塔的Climax钼公司的Sunil Jha引入了一种截然不同的制造超细钼粉的工艺。该产品的高比表面积现已实现商业化生产,可以在较低的烧结温度下获得完全致密的零件。它还使Mo / Cu和Mo / Ag的加工更具成本效益,并且合金更易于制造成电子部件,例如散热器和电触点。通过聚结以改善处理性能,超细粉末还可用于MIM原料。原则上,纳米Mo的生产顺序与前一篇论文中描述的相同,但实际上却有很大不同。获得专利的方法涉及淬灭MoO_3蒸气以形成粒径为50-100 nm的纳米三氧化钼(NTO)颗粒(图25)。 NTO的表面积接近60m 2 / g,其表观密度在0.11-0.14g / cm 3的范围内。

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