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首页> 外文期刊>International Journal of Quantum Chemistry >Quantum Theory of Thermal Fluctuations in DNA Miniplasmids
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Quantum Theory of Thermal Fluctuations in DNA Miniplasmids

机译:DNA微粒中热涨落的量子理论

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摘要

A recent analysis of the normal modes of vibration of a ring formed from an elastic rod was taken as the basis of a theory of the classical (high-temperature limit) statistical thermodynamics of a canonical ensemble of DNA minicricles (miniplasmids), each having a given number N of base pairs and given linking number difference #DELTA#L_k. Here, the vibrational modes are taken to be quantum mechanical in nature, which, in effect, generalizes the treatment to all temperatures. It is found that significant differences between the ensemble average of the writhing number as determined from the general theory and that calculated using the classical formalism do not appear except at very low temperatures.
机译:最近对由弹性棒形成的环的正常振动模式进行的分析被用作经典的(高温极限)DNA微裂纹(微质粒)规范集合的统计热力学理论的基础。给定碱基对数N和给定链接数差#DELTA#L_k。在这里,振动模式本质上被认为是量子力学的,这实际上将处理推广到了所有温度。已经发现,根据通用理论确定的扭曲数的总体平均值与使用经典形式主义计算的扭曲平均值的总和之间只有在非常低的温度下才会出现显着差异。

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