EPR and Optical Absorption Studies of Cu2+ Ions in [ZnPd(CN)4(C4H12N2O2)] Single Crystals

B. Karabulut; R. Tapramaz; A. Karadag

首页> 外文期刊>Applied Magnetic Resonance >EPR and Optical Absorption Studies of Cu2+ Ions in [ZnPd(CN)4(C4H12N2O2)] Single Crystals

【24h】

EPR and Optical Absorption Studies of Cu2+ Ions in [ZnPd(CN)4(C4H12N2O2)] Single Crystals

机译：EPR和[ZnPd（CN）4（C4H12N2O2）]单晶中Cu2 +离子的光吸收研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A Cu2+-doped single crystal of catena-fra"s-bis(AL(2-hydroxyethyl)-ethylenediamine) zinc(II)-tetra-m-cyanopaladate(II) [ZnPd(CN)4(C4Hl2N2O2)] complex has been investigated by electron paramagnetic resonance (EPR) technique at room temperature EPR spectra indicate that Cu2+ ions substitute for magnetically equivalent Zn2+ ions and form octahedral complexes in [ZnPd(CN)4(C4H12N2O2)] hosts. The crystal field affecting the Cu2+ ion is nearly axial. The optical absorption studies show two bands at 322 nm (30864 cm"') and 634 nm (15337 cm"1) which confirm the axial symmetry The spin Hamiltonian parameters and the relevant wave function ate determined.

机译：曾有一种Cu2 +掺杂的单链双（双（AL（2-羟乙基）-乙二胺）锌（II）-四间氰基丙二酸酯（II）[ZnPd（CN）4（C4H12N2O2）]络合物的单晶。在室温下通过电子顺磁共振（EPR）技术研究的EPR谱表明，Cu2 +离子替代了磁性等效的Zn2 +离子，并在[ZnPd（CN）4（C4H12N2O2）]主体中形成八面体络合物，影响Cu2 +离子的晶体场几乎光吸收研究显示了在322 nm（30864 cm“'）和634 nm（15337 cm” 1）的两个波段，这证实了轴向对称性。确定了自旋哈密顿量参数和相关的波函数。

著录项

来源
《Applied Magnetic Resonance》 |2008年第2期|共7页
作者
B. Karabulut; R. Tapramaz; A. Karadag;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类电磁学、电动力学;
关键词

相似文献

外文文献
中文文献
专利

1. EPR and Optical Absorption Studies of Cu2+ Ions in [ZnPd(CN)4(C4H12N2O2)] Single Crystals [J] . B. Karabulut, R. Tapramaz, A. Karadag Applied Magnetic Resonance . 2008,第2期

机译：EPR和[ZnPd（CN）4（C4H12N2O2）]单晶中Cu2 +离子的光吸收研究
2. Single crystal EPR and optical absorption studies of Cu2+ ion in L-arginine sulphophosphate monohydrate - a nonlinear optical crystal [J] . Dhanuskodi S, Mary PAA, Rao PS Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2005,第4期

机译：L-精氨酸磺基磷酸一水合物中Cu2 +离子的单晶EPR和光吸收研究-非线性光学晶体
3. EPR and Optical Absorption Study of Cu2+ Ions Doped in Potassium Hexaaquazinc (II) Sulphate (PHZS) Single Crystals [J] . Ram Kripal, Madan Gopal Misra, Prashant Dwivedi Applied Magnetic Resonance . 2012,第2期

机译：六水合硫酸铅锌晶体中掺杂的Cu 2 + 离子的EPR和光吸收研究
4. EPR and Optical Absorption study of Cu~(2+) doped Lithium Sulphate Monohydrate (LSMH) Single Crystals [C] . K. Juliet Sheela, S. Radha Krishnan, V. M. Shanmugam, DAE Solid State Physics Symposium . 2016

机译：Cu〜（2+）掺杂锂硫酸锂一水合物（LSMH）单晶的EPR和光学吸收研究
5. PART I: ELECTRON PARAMAGNETIC RESONANCE STUDIES OF GADOLINIUM CATION IN SINGLE CRYSTALS. PART II: AN EPR INVESTIGATION OF DEUTERIUM ISOTOPE EFFECTS ON THE ZERO-FIELD SPLITTINGS OF OPTICALLY EXCITED TRIPLET MOLECULES IN SINGLE CRYSTALS AT 77 K. [D] . THORSELL, DAVID LINDEN. 1971

机译：第一部分：单晶中G阳离子的电子顺磁共振研究。第二部分：在77 K时，氘同位素对单晶体中光学激发三重态分子零场裂变的EPR研究。
6. Insights into the mechanism of X-ray-induced disulfide-bond cleavage in lysozyme crystals based on EPR optical absorption and X-ray diffraction studies [O] . Kristin A. Sutton, Paul J. Black, Kermit R. Mercer, -1

机译：基于EPR光吸收和X射线衍射研究的X射线诱导溶菌酶晶体中二硫键裂解的机理
7. EPR STUDIES OF THE HAMILTONIAN PARAMETERS OF THE SIMULTANEOUSudAXIAL AND ORTHORHOMBIC JAHN-TELLER SPECTRA OF Cu2+ IN Cd2(NH4)2(SO4)3udSINGLE CRYSTALS AT DIFFERENT TEMPERATURES [O] . Yerima J. B., Dikko A. B., De Dilip Kumar 2014

机译：同时 ud的哈密尔顿参数的EPR研究Cd2（NH4）2（SO4）3中Cu2 +的轴位和正交各向异性约翰·泰勒谱在不同温度下的单晶

EPR and Optical Absorption Studies of Cu2+ Ions in [ZnPd(CN)4(C4H12N2O2)] Single Crystals

摘要

著录项

相似文献

相关主题

期刊订阅