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首页> 外文期刊>Applied Magnetic Resonance >The Distribution Change of Relaxation Times in Cl-35 NQR for Phase Transitions in p-Dichlorobenzene
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The Distribution Change of Relaxation Times in Cl-35 NQR for Phase Transitions in p-Dichlorobenzene

机译:对二氯苯中相变的Cl-35 NQR中弛豫时间的分布变化

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The results of an experimental study of phase transitions in molecular crystal of paradichlorobenzene by the nuclear quadrupole resonance relaxometry method with inversion of the Laplace transform are described in the article. The distributions of relaxation times T (1), T (1 rho) and for alpha- and beta-phases of p-C6H4Cl2 are measured. It is determined, that spin-spin relaxation times have unimodal distributions for alpha- and beta-phases, and spin-lattice relaxation times, including in rotating system of coordinates-multimodal distributions. It has been shown that spontaneous beta -> alpha phase transition does not arise in the porous material preliminary impregnated with the fused sample and the beta-phase is steadily retained.
机译:文章描述了通过对核四极共振弛豫法与拉普拉斯变换的反演对对二氯苯分子晶体的相变的实验研究结果。测量了弛豫时间T(1),T(1 rho)以及p-C6H4Cl2的α和β相的分布。已经确定,自旋-自旋弛豫时间具有α-和β-相的单峰分布,以及自旋-晶格弛豫时间,包括在坐标-多峰分布的旋转系统中。已经表明,在预先浸渍有熔融样品的多孔材料中不会出现自发的β→α相变,并且β相被稳定地保留。

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